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- W1975173255 abstract "The first example of alkane oxygenation with hydrogen peroxide catalyzed by a non-transition metal derivative (aluminium) is reported. Heating (70 °C) a solution of an alkane, RH, hydrogen peroxide (70% aqueous) and a catalytic amount of Al(NO3)3·9H2O in air for a few hours afforded the corresponding alkyl hydroperoxide, ROOH. With cyclooctane, the hydroperoxide yield attained 31% and the maximum turnover number was 150. It is proposed on the basis of measurements of the selectivity parameters for the oxidation of linear and branched alkanes and a kinetic study that the oxidation occurs with the participation of hydroxyl radicals." @default.
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- W1975173255 date "2008-11-01" @default.
- W1975173255 modified "2023-10-17" @default.
- W1975173255 title "Hydroperoxidation of alkanes with hydrogen peroxide catalyzed by aluminium nitrate in acetonitrile" @default.
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- W1975173255 doi "https://doi.org/10.1016/j.tetlet.2008.09.058" @default.
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