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- W1975201705 abstract "Selenium dioxide oxidation of cholesterol reveals a solvent-dependent product selectivity and facile one-pot synthesis of three derivatives, including aromatic analogues of naturally occurring ergosterol. Efficient access to 4β,7α-dihydroxy cholesterol is described. Analogous chemistry of β-sitosterol and diosgenin is also reported. The protocol is found effective to synthesize two diaromatic ergosterol natural products. A brief description of the molecular structures of the representative diaromatic cholesterol derivative and the triacetylated 4β,7α-dihydroxy cholesterol derivative are proven by X-ray crystallography." @default.
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- W1975201705 date "2012-08-01" @default.
- W1975201705 modified "2023-09-24" @default.
- W1975201705 title "Oxidation with selenium dioxide: the first report of solvent-selective steroidal aromatization, efficient access to 4β,7α-dihydroxy steroids, and syntheses of natural diaromatic ergosterols" @default.
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- W1975201705 doi "https://doi.org/10.1016/j.tet.2012.05.110" @default.
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