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• W1975294274 abstract "We report on x-ray scattering experiments of sodium and lithium doped polyacetylene in which the structure parallel to the polymer chains (along the c-axis) is probed using recently developed in-situ electro-chemical techniques. As expected, the c-axis lattice spacing increases as the Π-electron density is increased by electron transfer from the alkali dopant onto the polymer backbone. Contrary to theoretical predictions, however, the initial slope is zero and there appears to be a threshold for c-axis expansion at a Na+ concentration of ≈ 6 Mole % The results are consistent with the formation of a soliton lattice at light to moderate doping levels." @default.
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• W1975294274 date "1988-12-01" @default.
• W1975294274 modified "2023-09-26" @default.
• W1975294274 title "The relationship between charge transfer and structure in alkali doped polyacetylene" @default.
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• W1975294274 doi "https://doi.org/10.1016/0038-1098(88)90821-6" @default.
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