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- W1975362644 abstract "The crystal structure of CaMn7O12 has been studied by high-resolution neutron and synchrotron radiation diffraction between 10 and 400K. The unusual geometrical properties of the Mn–O bonds network in CaMn7O12 are discussed. The thermal lattice expansion is anisotropic—the hexagonal lattice parameter c has a local maximum around 50K and a local minimum at 250K. The MnO6 octahedra around Mn3+ ions are apically Jahn-Teller distorted with two pairs of long ∼2.04,∼2.03Å and one short ∼1.89Å bonds without significant changes with temperature. There are weak peaks in the SR diffraction patterns which are due to a charge modulation, and which disappear above TCM=250K. The maximum and minimum of the c-lattice parameter correlates with the magnetic phase transition at TC=49K and the charge ordering transition TCM=250K, respectively." @default.
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- W1975362644 date "2004-02-01" @default.
- W1975362644 modified "2023-09-27" @default.
- W1975362644 title "Charge ordering and anisotropic thermal expansion of the manganese perovskite CaMn7O12" @default.
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- W1975362644 doi "https://doi.org/10.1016/j.physb.2003.10.013" @default.
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