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• W1975448547 endingPage "113" @default.
• W1975448547 startingPage "91" @default.
• W1975448547 abstract "Radial diffusion of solutes in the mobile phase limits the practical linear velocities that can be used to increase speed of analysis in conventional open tubular column chromatography. Several methods have been devised to enhance radial dispersion that do not depend only on molecular radial diffusion. In this review, the methods of enhancing dispersion found in the chromatographic literature are discussed. These methods include the use of deformed columns, and spinning band and static mixer columns. These techniques have been found to be of little value in analytical chromatography. Electroosmotic flow has been used to generate a plug-like flow profile in LC and generates one to two orders of magnitude lower plate height than produced at laminar flow conditions. Turbulent and secondary flow have been used to enhance radial diffusion in open tubular columns for gas, liquid, and supercritical fluid chromatography. These techniques are described from their theoretical and practical aspects. Turbulent flow has been investigated as a means for enhancing radial dispersion in open tubular column chromatography for several years. At low linear velocities (Reynolds numbers < 2000), the Golay equation accurately predicts that increasing velocities generate higher plate heights. However, turbulent flow experimental results have shown that unretained solutes have decreasing plate heights with increasing velocity after a critical velocity is achieved. Up to this time, turbulent flow chromatography has not been shown to be useful for retained solutes, and applications in analytical separations are absent in the literature. Secondary flow has also been studied by several investigators for the enhancement of radial dispersion. A circular, radial flow profile can be generated by centrifugal forces in tightly coiled columns, and after a critical velocity is achieved, columns coiled to appropriate aspect ratios yield lower plate heights than straight columns for unretained solutes as the velocity is increased. Although retained solutes yield higher plate heights in coiled rather than conventional straight columns in some cases due to the resistance to mass transfer at the interphase region, higher speeds of analysis are obtained. Secondary flow chromatography has been successfully applied in gas and supercritical fluid chromatography for the rapid separation of alkanes having low retention. Nevertheless, applications using secondary flow in chromatographic separations are limited." @default.
• W1975448547 created "2016-06-24" @default.
• W1975448547 creator A5050371313 @default.
• W1975448547 creator A5053151918 @default.
• W1975448547 date "1991-03-01" @default.
• W1975448547 modified "2023-09-25" @default.
• W1975448547 title "Enhanced radial dispersion in open tubular column chromatography" @default.
• W1975448547 cites W1519298538 @default.
• W1975448547 cites W15241962 @default.
• W1975448547 cites W1552868515 @default.
• W1975448547 cites W1964850194 @default.
• W1975448547 cites W1969572219 @default.
• W1975448547 cites W1969877778 @default.
• W1975448547 cites W1972543495 @default.
• W1975448547 cites W1973036269 @default.
• W1975448547 cites W1973869354 @default.
• W1975448547 cites W1974511821 @default.
• W1975448547 cites W1974561594 @default.
• W1975448547 cites W1976049974 @default.
• W1975448547 cites W1979431647 @default.
• W1975448547 cites W1982688043 @default.
• W1975448547 cites W1983921648 @default.
• W1975448547 cites W1985957199 @default.
• W1975448547 cites W1986346379 @default.
• W1975448547 cites W1986730242 @default.
• W1975448547 cites W1988154656 @default.
• W1975448547 cites W1991039757 @default.
• W1975448547 cites W1991798637 @default.
• W1975448547 cites W1994396294 @default.
• W1975448547 cites W1996818420 @default.
• W1975448547 cites W1999502789 @default.
• W1975448547 cites W2001480669 @default.
• W1975448547 cites W2002795538 @default.
• W1975448547 cites W2003333956 @default.
• W1975448547 cites W2003650182 @default.
• W1975448547 cites W2004492852 @default.
• W1975448547 cites W2013007595 @default.
• W1975448547 cites W2013542909 @default.
• W1975448547 cites W2013902575 @default.
• W1975448547 cites W2017013327 @default.
• W1975448547 cites W2021992136 @default.
• W1975448547 cites W2022396314 @default.
• W1975448547 cites W2022911140 @default.
• W1975448547 cites W2028873860 @default.
• W1975448547 cites W2033719815 @default.
• W1975448547 cites W2034784548 @default.
• W1975448547 cites W2039072678 @default.
• W1975448547 cites W2043575119 @default.
• W1975448547 cites W2044488237 @default.
• W1975448547 cites W2046752255 @default.
• W1975448547 cites W204742082 @default.
• W1975448547 cites W2047918494 @default.
• W1975448547 cites W2053776751 @default.
• W1975448547 cites W2053788556 @default.
• W1975448547 cites W2058746843 @default.
• W1975448547 cites W2059563714 @default.
• W1975448547 cites W2060181854 @default.
• W1975448547 cites W2062397554 @default.
• W1975448547 cites W2063260308 @default.
• W1975448547 cites W2063681717 @default.
• W1975448547 cites W2069784453 @default.
• W1975448547 cites W2070111099 @default.
• W1975448547 cites W2071381169 @default.
• W1975448547 cites W2072838740 @default.
• W1975448547 cites W2073834617 @default.
• W1975448547 cites W2076443152 @default.
• W1975448547 cites W2077004455 @default.
• W1975448547 cites W2080564863 @default.
• W1975448547 cites W2081129078 @default.
• W1975448547 cites W2082284887 @default.
• W1975448547 cites W2085011505 @default.
• W1975448547 cites W2085185740 @default.
• W1975448547 cites W2088022249 @default.
• W1975448547 cites W2088110305 @default.
• W1975448547 cites W2091056966 @default.
• W1975448547 cites W2102044202 @default.
• W1975448547 cites W2110521640 @default.
• W1975448547 cites W2110785780 @default.
• W1975448547 cites W2120674960 @default.
• W1975448547 cites W2122873975 @default.
• W1975448547 cites W2126117450 @default.
• W1975448547 cites W2131021574 @default.
• W1975448547 cites W2137226459 @default.
• W1975448547 cites W2138652474 @default.
• W1975448547 cites W2150908121 @default.
• W1975448547 cites W2151577896 @default.
• W1975448547 cites W2159214896 @default.
• W1975448547 cites W2168454518 @default.
• W1975448547 cites W2168517693 @default.
• W1975448547 cites W2312381510 @default.
• W1975448547 cites W2315802634 @default.
• W1975448547 cites W2318079507 @default.
• W1975448547 cites W2318214654 @default.
• W1975448547 cites W2319726547 @default.
• W1975448547 cites W2325092910 @default.
• W1975448547 cites W2331758028 @default.
• W1975448547 cites W2913039377 @default.
• W1975448547 cites W2942175741 @default.

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