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- W1975471995 abstract "Electrochemical fluorinations of 2-fluorotoluene (2a), 3-fluorotoluene (3a) and 4-fluorotoluene (4a) in neat Et4NF · mHF (Et = C2H5, m = 3.5 or 4.0) were carried out on a platinum anode. The fluorination of 2a, 3a and 4a occurred competitively both on the side-chain (formation of monofluoromethylfluorobenzenes) and on the benzene-ring (formation of methyltrifluoro-1,4-cyclohexadienes). These results are explained by the facility of proton eliminaticn from the methyl groups of the radical cations which have been formed by the anodic one-electron transfer reactions of 2a, 3a and 4a. A cyclic voltammogram of 4a showed three anodic current peaks which correspond to the oxidation of 4a, 1-fluoromethyl-4-fiuorobenzene (4b) and 1-difluoromethyl-4-fluorolbenzene (4c). On the other hand, voltammograms of 2a and 3a showed two anodic current peaks and no difluoromethylfluorobenzenes was obtained during the fluorination of 2a and 3a." @default.
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- W1975471995 date "1998-02-01" @default.
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- W1975471995 title "Competitive fluorination on methyl-group and benzene-ring during the anodic fluorination of fluorotoluenes in Et4NF · mHF" @default.
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- W1975471995 doi "https://doi.org/10.1016/s0022-1139(97)00141-3" @default.
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