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- W1975496502 abstract "Tricarbonyl iron complexes of acyclic 1,3-dienes can be converted to conjugated cyclopentenones by decomplexation with aluminium halides. Most complexes of a simple dienes need drastic conditions for the cyclocarbonylation to occur (100 Atm CO, 1000° C), with the exception of 1,1,3-trialkylbutadiene complexes which are nearly quantitatively converted into cyclopentenones at room temperature, even in the absence of a CO atmosphere. Under the same mild conditions, the other complexes lead in modest yields to cyclopentadienyl dicarbonyl iron halides by a cyclocarbonylation reaction followed by an aluminium halide promoted deoxygenation." @default.
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- W1975496502 date "1992-11-01" @default.
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- W1975496502 title "Cyclocarbonylation of acyclic 1,3-dienes via their tricarbonyl iron complexes : Cyclopenten-2-ones and dicarbonyl cyclopentadienyl iron halides" @default.
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- W1975496502 doi "https://doi.org/10.1016/s0040-4039(00)60188-0" @default.
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