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- W1975528069 abstract "The reaction of ButCP with Na/Hg in monoglyme results in the formation of the 2,5-di-t-butyl-1,3,4-triphosphacyclopentadienyl (1) and 2,4,5-tri-t-butyl-1,3-diphosphacyclopentadienyl (2) anions. The reaction has been carried out in the absence of [Ta(OAr)2Cl3] (Ar = 4-Me,2,6-t-Bu2C6H2), which proves that the formation of 1 and 2 does not involve the phosphide intermediate [TaP(OAr)2] previously postulated by Cowley and Hall (Polyhedron 1989, 8, 849)." @default.
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- W1975528069 date "1989-01-01" @default.
- W1975528069 modified "2023-10-16" @default.
- W1975528069 title "Cleavage of the pc triple bond in a phospha-alkyne in the absence of a transition metal" @default.
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- W1975528069 doi "https://doi.org/10.1016/s0277-5387(00)80304-6" @default.
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