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Matches in SemOpenAlex for { <https://semopenalex.org/work/W1975549830> ?p ?o ?g. }

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• W1975549830 abstract "The complex 2-allyl-6-methylphenoxocopper(I) has been prepared by reaction between mesitylcopper(I) and 2-allyl-6-methylphenol. Crystallographic studies show that the compound is tetrameric with a distorted cubane-type copper(I)-oxygen core, and with additional π-coordination of the ligand to copper through the alkene functionality (ν(CC)=1520 cm−1). The ligands thus act both as chelates and as bridges between adjacent copper(I) centres. Copper(I) exhibits trigonal pyramidal coordination geometry with CuC distances to the CC group of 1.976(9) and 2.017(11) Å and CuO distances of 1.973(6), 2.021(6) and 2.577(6) Å, respectively." @default.
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• W1975549830 date "2002-04-01" @default.
• W1975549830 modified "2023-10-18" @default.
• W1975549830 title "A tetrameric copper(I) alkoxide with a π-tethered ligand: 2-allyl-6-methylphenoxocopper(I)" @default.
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• W1975549830 doi "https://doi.org/10.1016/s0022-328x(02)01126-9" @default.
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