FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1975566877> ?p ?o ?g. }

• W1975566877 endingPage "1584" @default.
• W1975566877 startingPage "1584" @default.
• W1975566877 abstract "Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(II) and platinum(II) with the formulae [MX2L2] (M = Pd, Pt and X = Cl, Br, I): [Pd2Cl2(μ-Cl)2L2], [PdCl(S2CNEt2)L] and [Pd2Cl2(μ-dmpz)2L2] [L = As(CH2CHCH2)3 (L′), As(CH2CMeCH2)3 (L″), dmpz = 3,5-dimethylpyrazolate] have been prepared. All the complexes have been characterized by elemental analyses and by IR and NMR (1H, 13C, 195Pt) spectroscopy. The stereochemistry of the complexes has been deduced from the spectroscopic data. The molecular structures of complexes [MX2{As(CH2CHCH2)3}2] (M = Pd, X = Cl or Br), [MX2{As(CH2CMeCH2)3}2] (M = Pd, X = Cl or Br; M = Pt, X = Cl) and [Pd2Cl2(μ-Cl)2{As(CH2CMeCH2)3}2] have been established by single crystal X-ray diffraction analyses. The mononuclear complexes exclusively adopt the trans configuration with the exception of [PdCl2L″2], which could be isolated as cis and trans isomers. In the binuclear derivative the arsine ligands are attached to an envelope-shaped Pd–(μ-Cl)2–Pd rectangle with a trans (anti) orientation towards each other. The mononuclear complexes are slightly photoreactive upon irradiation in their long-wavelength absorption band." @default.
• W1975566877 created "2016-06-24" @default.
• W1975566877 creator A5020043051 @default.
• W1975566877 creator A5030961872 @default.
• W1975566877 creator A5043245954 @default.
• W1975566877 creator A5046763720 @default.
• W1975566877 creator A5056827030 @default.
• W1975566877 date "2003-01-01" @default.
• W1975566877 modified "2023-09-23" @default.
• W1975566877 title "Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(ii) and platinum(ii): synthesis, spectroscopy, photochemistry and structures" @default.
• W1975566877 cites W1975035035 @default.
• W1975566877 cites W1985951761 @default.
• W1975566877 cites W1998406931 @default.
• W1975566877 cites W2006897747 @default.
• W1975566877 cites W2012164247 @default.
• W1975566877 cites W2018398986 @default.
• W1975566877 cites W2018695811 @default.
• W1975566877 cites W2034201475 @default.
• W1975566877 cites W2040712265 @default.
• W1975566877 cites W2044691689 @default.
• W1975566877 cites W2046842007 @default.
• W1975566877 cites W2047251745 @default.
• W1975566877 cites W2050422732 @default.
• W1975566877 cites W2050700710 @default.
• W1975566877 cites W2053471920 @default.
• W1975566877 cites W2072982778 @default.
• W1975566877 cites W2085349375 @default.
• W1975566877 cites W2135452112 @default.
• W1975566877 cites W2147304506 @default.
• W1975566877 cites W2465889096 @default.
• W1975566877 cites W2508895453 @default.
• W1975566877 cites W2788782485 @default.
• W1975566877 cites W2943741765 @default.
• W1975566877 cites W2951359007 @default.
• W1975566877 cites W2952983696 @default.
• W1975566877 cites W3004471784 @default.
• W1975566877 cites W615164098 @default.
• W1975566877 doi "https://doi.org/10.1039/b303990k" @default.
• W1975566877 hasPublicationYear "2003" @default.
• W1975566877 type Work @default.
• W1975566877 sameAs 1975566877 @default.
• W1975566877 citedByCount "26" @default.
• W1975566877 countsByYear W19755668772013 @default.
• W1975566877 countsByYear W19755668772014 @default.
• W1975566877 countsByYear W19755668772015 @default.
• W1975566877 countsByYear W19755668772016 @default.
• W1975566877 countsByYear W19755668772017 @default.
• W1975566877 countsByYear W19755668772020 @default.
• W1975566877 crossrefType "journal-article" @default.
• W1975566877 hasAuthorship W1975566877A5020043051 @default.
• W1975566877 hasAuthorship W1975566877A5030961872 @default.
• W1975566877 hasAuthorship W1975566877A5043245954 @default.
• W1975566877 hasAuthorship W1975566877A5046763720 @default.
• W1975566877 hasAuthorship W1975566877A5056827030 @default.
• W1975566877 hasConcept C121332964 @default.
• W1975566877 hasConcept C155647269 @default.
• W1975566877 hasConcept C161790260 @default.
• W1975566877 hasConcept C176788430 @default.
• W1975566877 hasConcept C178790620 @default.
• W1975566877 hasConcept C185592680 @default.
• W1975566877 hasConcept C2776776902 @default.
• W1975566877 hasConcept C2777716191 @default.
• W1975566877 hasConcept C32891209 @default.
• W1975566877 hasConcept C502130503 @default.
• W1975566877 hasConcept C518104683 @default.
• W1975566877 hasConcept C62520636 @default.
• W1975566877 hasConcept C71240020 @default.
• W1975566877 hasConcept C75473681 @default.
• W1975566877 hasConcept C8010536 @default.
• W1975566877 hasConceptScore W1975566877C121332964 @default.
• W1975566877 hasConceptScore W1975566877C155647269 @default.
• W1975566877 hasConceptScore W1975566877C161790260 @default.
• W1975566877 hasConceptScore W1975566877C176788430 @default.
• W1975566877 hasConceptScore W1975566877C178790620 @default.
• W1975566877 hasConceptScore W1975566877C185592680 @default.
• W1975566877 hasConceptScore W1975566877C2776776902 @default.
• W1975566877 hasConceptScore W1975566877C2777716191 @default.
• W1975566877 hasConceptScore W1975566877C32891209 @default.
• W1975566877 hasConceptScore W1975566877C502130503 @default.
• W1975566877 hasConceptScore W1975566877C518104683 @default.
• W1975566877 hasConceptScore W1975566877C62520636 @default.
• W1975566877 hasConceptScore W1975566877C71240020 @default.
• W1975566877 hasConceptScore W1975566877C75473681 @default.
• W1975566877 hasConceptScore W1975566877C8010536 @default.
• W1975566877 hasIssue "11" @default.
• W1975566877 hasLocation W19755668771 @default.
• W1975566877 hasOpenAccess W1975566877 @default.
• W1975566877 hasPrimaryLocation W19755668771 @default.
• W1975566877 hasRelatedWork W1984306190 @default.
• W1975566877 hasRelatedWork W1990112900 @default.
• W1975566877 hasRelatedWork W2006809866 @default.
• W1975566877 hasRelatedWork W2042910999 @default.
• W1975566877 hasRelatedWork W2101524511 @default.
• W1975566877 hasRelatedWork W2114738851 @default.
• W1975566877 hasRelatedWork W2188739058 @default.
• W1975566877 hasRelatedWork W2949084089 @default.
• W1975566877 hasRelatedWork W2984735441 @default.
• W1975566877 hasRelatedWork W4234139979 @default.

• next