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- W1975583459 abstract "Differential scanning calorimetry (DSC) was used to investigate the freezing behaviour (−175°C to 20°C) of hardened cement paste (hcp) subjected to NaCl and CaCl2 solutions containing up to 5.4 mol Cl/l. Thermograms were also recorded for samples dried to relative humidities (RH) between 61 % and 96 %. The low-temperature phase transition at −38°C exhibited the freezing behaviour of an aqueous solution in gel pores of ≈ 4 nm radius. Chloride ions strongly reduce the coupling forces between gel particles and structure the gel pore water. On desorption critical behaviour of the low-temperature transition energy was observed at 0.52 mol Cl/l which is the concentration most damaging to hcp. Above 1.3 mol Cl/l freezing of supercooled bulk water in macropores was observed at more than one temperature." @default.
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- W1975583459 date "1988-03-01" @default.
- W1975583459 modified "2023-09-27" @default.
- W1975583459 title "A low-temperature DSC investigation of hardened cement paste subjected to chloride action" @default.
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- W1975583459 doi "https://doi.org/10.1016/0008-8846(88)90009-9" @default.
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