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- W1975592306 abstract "Abstract Ethoxyacetylene (I) has been converted by organocopper(I) species into (E)-2-ethoxy-1-alkenylcopper(I) compounds (II). The adducts II have been shown to be useful intermediates for preparation of 1,4-diketones (VI). Two routes to VI were used: (i) sequential treatment of II with allyl bromide, 3.0 N HCl, and PdCl2/CuCl in DMF/H2O, and (ii) sequential treatment of II with 2,3-dibromopropene and Hg(OAc)2. A dienone was formed from the first procedure when after the reaction of II with allyl bromide the product was treated first with the PdCl2/CuCl." @default.
- W1975592306 created "2016-06-24" @default.
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- W1975592306 date "1986-02-01" @default.
- W1975592306 modified "2023-10-09" @default.
- W1975592306 title "Ethoxyacetylene: A useful building block for the organocopper(I) mediated synthesis of 1,4-diketones" @default.
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- W1975592306 doi "https://doi.org/10.1016/0022-328x(86)80015-8" @default.
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