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- W1975665521 abstract "A method of calculating the ground state thermal dissociation energy and the electronic part of the optical (1s-2p) absorption energy of a colour centre in an ionic crystal is outlined. The electrostatic energy of interaction of the trapped electron and the lattice is determined by the summation of individual terms due to lattice charges and to dipoles induced at the lattice points. Polarizabilities of these dipoles can be determined readily from the results of Mott and Littleton for NaCl. The calculated thermal dissociation energy for this material is within 10% of the experimental value. A direct comparison with experiment for the optical absorption energy is not possible because of the relatively large lattice oscillator term which is not determined by the present method. A comparison with the results of Huang and Rhys for KBr indicates, however, that the electronic component of the absorption energy for NaCl here calculated is approximately correct." @default.
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- W1975665521 date "1958-05-01" @default.
- W1975665521 modified "2023-09-27" @default.
- W1975665521 title "On the Thermal and Optical Excitation of Colour Centres" @default.
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- W1975665521 doi "https://doi.org/10.1088/0370-1328/71/5/307" @default.
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