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• W1975667937 endingPage "2242" @default.
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• W1975667937 abstract "The preparation of thorium phosphate-diphosphate (Th4(PO4)4P2O7, TPD) was developed through the precipitation of thorium phosphate-hydrogenphosphate hydrate (Th2(PO4)2(HPO4)·H2O, TPHPH) at 150–160 °C in closed PTFE container or in autoclaves. From EPMA analyses and SEM observations, the initial precipitate was single phase and multilayered. The behaviour of TPHPH (orthorhombic system with a = 21.368(2) Å, b = 6.695(1) Å and c = 7.023(1) Å) was followed when heating up to 1250 °C. It was first dehydrated leading to the anhydrous thorium phosphate-hydrogenphosphate (TPHP, orthorhombic system with a = 21.229(2) Å, b = 6.661(1) Å and c = 7.031(1) Å at 220 °C) after heating between 180 and 200 °C. This one turned progressively into the new low-temperature variety of TPD (called α-TPD, orthorhombic system with a = 21.206(2) Å, b = 6.657(1) Å and c = 7.057(1) Å at 300 °C) correlatively to the condensation of hydrogenphosphate groups into diphosphate entities. These three phases (TPHPH, TPHP and α-TPD) exhibit closely related 2D layered structures, therefore different from the 3D structure of the thorium phosphate-diphosphate (high-temperature variety). This latter compound, now called β-TPD, was obtained by heating α-TPD above 950 °C. All the techniques involved in this study (XRD, Raman and IR spectroscopy, 1H and 31P NMR) confirmed the successive chemical reactions proposed." @default.
• W1975667937 created "2016-06-24" @default.
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• W1975667937 date "2005-12-01" @default.
• W1975667937 modified "2023-10-02" @default.
• W1975667937 title "Characterization of the thorium phosphate-hydrogenphosphate hydrate (TPHPH) and study of its transformation into the thorium phosphate-diphosphate (β-TPD)" @default.
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• W1975667937 doi "https://doi.org/10.1016/j.materresbull.2005.06.011" @default.
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