Matches in SemOpenAlex for { <https://semopenalex.org/work/W1975688317> ?p ?o ?g. }
- W1975688317 endingPage "169" @default.
- W1975688317 startingPage "158" @default.
- W1975688317 abstract "Reaction of 1,3-bis(2′-Ar-imino)isoindolines (HLn, n = 1–7, Ar = benzimidazolyl, N-methylbenzimidazolyl, thiazolyl, pyridyl, 3-methylpyridyl, 4-methylpyridyl, and benzthiazolyl, respectively) with Cu(OCH3)2 yields mononuclear hexacoordinate complexes with Cu(Ln)2 composition. With cupric perchlorate square-pyramidal [CuII(HLn)(NCCH3)(OClO3)]ClO4 complexes (n = 1, 3, 4) were isolated as perchlorate salts, whereas with chloride CuII(HLn)Cl2 (n = 1, 4), or square-planar CuIICl2(HLn) (n = 2, 3, 7) complexes are formed. The X-ray crystal structures of Cu(L3)2, Cu(L5)2, [CuII(HL4)(NCCH3)(OClO3)]ClO4, CuIICl(L2) and CuIICl(L7) are presented along with electrochemical and spectral (UV–Vis, FT-IR and X-band EPR) characterization for each compound. When combined with base, the isoindoline ligands in the [CuII(HLn)(NCCH3)(OClO3)]ClO4 complexes undergo deprotonation in solution that is reversible and induces UV–Vis spectral changes. Equilibrium constants for the dissociation are calculated. X-band EPR measurements in frozen solution show that the geometry of the complexes is similar to the corresponding X-ray crystallographic structures. The superoxide scavenging activity of the compounds determined from the McCord–Fridovich experiment show dependence on structural features and reduction potentials." @default.
- W1975688317 created "2016-06-24" @default.
- W1975688317 creator A5004048686 @default.
- W1975688317 creator A5007150877 @default.
- W1975688317 creator A5009570331 @default.
- W1975688317 creator A5044231851 @default.
- W1975688317 creator A5045488288 @default.
- W1975688317 creator A5056608406 @default.
- W1975688317 creator A5087292468 @default.
- W1975688317 creator A5087889425 @default.
- W1975688317 creator A5091840593 @default.
- W1975688317 date "2011-10-01" @default.
- W1975688317 modified "2023-10-09" @default.
- W1975688317 title "Tetra-, penta- and hexacoordinate copper(II) complexes with N3 donor isoindoline-based ligands: Characterization and SOD-like activity" @default.
- W1975688317 cites W1171346759 @default.
- W1975688317 cites W1574629827 @default.
- W1975688317 cites W1591841427 @default.
- W1975688317 cites W1781803186 @default.
- W1975688317 cites W1820406695 @default.
- W1975688317 cites W1940436875 @default.
- W1975688317 cites W1952402412 @default.
- W1975688317 cites W1961139916 @default.
- W1975688317 cites W1964220021 @default.
- W1975688317 cites W1970459421 @default.
- W1975688317 cites W1971839598 @default.
- W1975688317 cites W1975041221 @default.
- W1975688317 cites W1975911266 @default.
- W1975688317 cites W1978237516 @default.
- W1975688317 cites W1978974747 @default.
- W1975688317 cites W1979259874 @default.
- W1975688317 cites W1982203427 @default.
- W1975688317 cites W1983066183 @default.
- W1975688317 cites W1983318752 @default.
- W1975688317 cites W1983986347 @default.
- W1975688317 cites W1984148103 @default.
- W1975688317 cites W1987062656 @default.
- W1975688317 cites W1988256687 @default.
- W1975688317 cites W1990960774 @default.
- W1975688317 cites W1994245840 @default.
- W1975688317 cites W1997185763 @default.
- W1975688317 cites W2005358242 @default.
- W1975688317 cites W2009108184 @default.
- W1975688317 cites W2010672074 @default.
- W1975688317 cites W2014075564 @default.
- W1975688317 cites W2019393729 @default.
- W1975688317 cites W2024765301 @default.
- W1975688317 cites W2026811488 @default.
- W1975688317 cites W2034083429 @default.
- W1975688317 cites W2035691001 @default.
- W1975688317 cites W2036720621 @default.
- W1975688317 cites W2037128300 @default.
- W1975688317 cites W2037804096 @default.
- W1975688317 cites W2037825412 @default.
- W1975688317 cites W2038492424 @default.
- W1975688317 cites W2038669999 @default.
- W1975688317 cites W2042109608 @default.
- W1975688317 cites W2042642397 @default.
- W1975688317 cites W2042731312 @default.
- W1975688317 cites W2046046571 @default.
- W1975688317 cites W2048747402 @default.
- W1975688317 cites W2052488539 @default.
- W1975688317 cites W2052789784 @default.
- W1975688317 cites W2052999189 @default.
- W1975688317 cites W2056210471 @default.
- W1975688317 cites W2057607512 @default.
- W1975688317 cites W2063220152 @default.
- W1975688317 cites W2065844263 @default.
- W1975688317 cites W2067836734 @default.
- W1975688317 cites W2069772558 @default.
- W1975688317 cites W2071090277 @default.
- W1975688317 cites W2072630128 @default.
- W1975688317 cites W2072644260 @default.
- W1975688317 cites W2076633051 @default.
- W1975688317 cites W2078048204 @default.
- W1975688317 cites W2081373204 @default.
- W1975688317 cites W2083631371 @default.
- W1975688317 cites W2085513447 @default.
- W1975688317 cites W2088000936 @default.
- W1975688317 cites W2088476033 @default.
- W1975688317 cites W2088558274 @default.
- W1975688317 cites W2092912053 @default.
- W1975688317 cites W2093220503 @default.
- W1975688317 cites W2105249240 @default.
- W1975688317 cites W2105442888 @default.
- W1975688317 cites W2117180069 @default.
- W1975688317 cites W2130671015 @default.
- W1975688317 cites W2142491754 @default.
- W1975688317 cites W2148616203 @default.
- W1975688317 cites W2165201155 @default.
- W1975688317 cites W2324469337 @default.
- W1975688317 cites W2949110010 @default.
- W1975688317 cites W2950657871 @default.
- W1975688317 cites W2951293334 @default.
- W1975688317 cites W2951749359 @default.
- W1975688317 doi "https://doi.org/10.1016/j.ica.2011.06.001" @default.
- W1975688317 hasPublicationYear "2011" @default.
- W1975688317 type Work @default.
- W1975688317 sameAs 1975688317 @default.