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- W1975787759 abstract "An analysis of Ca2+ influence on the thermotropic behaviour of different phosphatidylcholine-vitamin D3 mixtures was carried out by differential scanning calorimetry technique (DSC). A competitive effect between Ca2− and vitamin D3 on the membrane fluidity was detected. The observed shifts of the gel-liquid crystal transition temperature were correlated with the mole fraction of vitamin D3 dissolved within the lipid bilayer as well as with the Ca2+ concentration in the surrounding medium. These shifts were rationalized on the ground of a simple microscopic model through the calculation of the internal pressure exerted by the adsorbed Ca2− on the lipid matrix by the Clapeyron equation. The experimental results and the obtained equations accord with each other and support the idea of micro-domain formation richer in one lipid component. The extent of such lateral phase separation of the lipid components seems to be favoured by the adsorption of Ca2+ at the membrane-water interface." @default.
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- W1975787759 date "1990-01-01" @default.
- W1975787759 modified "2023-10-03" @default.
- W1975787759 title "Calcium ion influence on thermotropic behaviour of dipalmitoylphosphatidylcholine-vitamin D3 systems" @default.
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- W1975787759 doi "https://doi.org/10.1016/0009-3084(90)90156-l" @default.
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