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- W1975792007 abstract "Crystal growth of boron phosphide (BP) has been investigated using our unique high pressure flux method in which BP is recrystallized from a copper phosphide solution in a temperature gradient under high pressures. BP single crystals of 5 × 5 × 3 mm3, the largest as far as we know, having well developed smooth (111) planes were obtained. According to the X-ray powder diffraction pattern there is a small amount of B6P precipitate and the crystal has a lattice constant of a = 4539 A. Copper is detected by X-ray fluorescence analysis. The crystals exhibit p-type conduction with the electrical resistivity, carrier concentration and hole mobility of 1.5 Ω cm, 1.67 × 1018 cm-3 and 1.77 cm2/V ⋯ s, respectively. The photoluminescence spectrum at 4.2 K consists of five bands. The peaks caused by donor-acceptor pairs are obtained, which is in good agreement with the theoretical value of the type II peak in phosphides with a zincblende structure. These crystals can be utilized as substrates for epitaxial growth." @default.
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- W1975792007 date "1984-12-01" @default.
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- W1975792007 title "Crystal growth of boron phosphide by high pressure flux method" @default.
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- W1975792007 doi "https://doi.org/10.1016/0022-0248(84)90310-5" @default.
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