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• W1975827615 abstract "We present transient resonance Raman experiments done to obtain a vibrational spectrum of the photoproduct species associated with the ∼570 nm transient absorption band observed after ultraviolet photolysis of CH2I2 in the solution phase. The experimental vibrational frequencies and their isotopic shifts are compared to results of density functional theory calculations for the probable photoproduct species. Our results show that both the CH2I2+ cation and iso-CH2I−I species contribute to the transient ∼570 nm absorption band. The relative amounts of CH2I2+ cation and iso-CH2I−I species observed depend on the power of the 532 nm probe laser beam. We briefly discuss the qualitative properties of the visible electronic transitions of the CH2I2+ cation and iso-CH2I−I species." @default.
• W1975827615 created "2016-06-24" @default.
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• W1975827615 creator A5067405994 @default.
• W1975827615 date "2001-12-12" @default.
• W1975827615 modified "2023-10-01" @default.
• W1975827615 title "Transient Resonance Raman Investigation of the ∼570 nm Transient Absorption Band Observed after Ultraviolet Photolysis of Diiodomethane in the Solution Phase" @default.
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• W1975827615 doi "https://doi.org/10.1021/jp012608f" @default.
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