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• W1975883826 endingPage "817" @default.
• W1975883826 startingPage "812" @default.
• W1975883826 abstract "Abstract An efficient method for the syntheses of cyclopentitols from d -ribose is described using Nozaki–Hiyama–Kishi conditions and ring closing metathesis. In this transformation ω-deoxy-ω-iodo ribofuranoside undergoes reductive elimination in the presence of CrCl 2 to give the corresponding olefin-aldehyde, which was trapped by a nucleophile under the same conditions to afford the desired diolefinic species. The ring closing metathesis reaction on the diolefinic species with a Grubbs second generation catalyst produced the required carbocycles." @default.
• W1975883826 created "2016-06-24" @default.
• W1975883826 creator A5009675042 @default.
• W1975883826 creator A5041599253 @default.
• W1975883826 date "2011-04-01" @default.
• W1975883826 modified "2023-09-26" @default.
• W1975883826 title "A new approach to cyclopentitols using CrCl2 mediated domino reaction and ring closing metathesis. The synthesis of 4a-carba-β-d-arabinofuranose and 4a-carba-β-d-lyxofuranose" @default.
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• W1975883826 doi "https://doi.org/10.1016/j.tetasy.2011.04.012" @default.
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