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- W1975901193 abstract "Synthesis of Cationic η2-Phosphinocarbene Complexes of Molybdenum and Tungsten1 Herrn Professor Hubert Schmidbaur zum 60. Geburtstag gewidmet. The reaction of chlordimethylphosphane or chlordiphenyl-phosphane and sodium tetraphenylborate with dicarbonyl(η5-cyclopentadienyl)carbyne complexes of molybdenum and tungsten enables the direct conversion of a MCR group into a MC(R)PR2 unit providing dicarbonyl substituted η2-phosphinocarbene complexes in high yields. In the absence of Na[BPh4] a base induced carbonyl carbene coupling reaction affords η3-phosphinoketene complexes." @default.
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- W1975901193 date "1995-03-01" @default.
- W1975901193 modified "2023-09-26" @default.
- W1975901193 title "Synthese kationischer η <sup>2</sup> ‐Phosphinocarben‐Komplexe des Molybdäns und Wolframs" @default.
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- W1975901193 doi "https://doi.org/10.1002/cber.19951280313" @default.
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