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- W1975927260 abstract "In 0·10 F HClO4, cis-Cr(pn)2Cl2+ has been found by spectrophotometric, Cl− release and chromatographic methods to aquate to the previously unreported species cis-Cr(pn)2(OH2)Cl2+; at 25·0°C the first-order constant is k1 = (3·5 ± 0·3) × 10−4 sec−1. At 25·0°C, cis-Cr(pn)2(OH2)Cl2+ hydrolyses in 3·1 F HClO4 with a pseudo first-order rate constant of k2 = (9·7) ± 0·9) × 10−6 sec−1, the product having been tentatively identified as a new complex, cis-Cr(pn)2(OH2)23+. Visible absorption spectra of the complexes are reported." @default.
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- W1975927260 date "1967-09-01" @default.
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- W1975927260 title "Kinetics of hydrolysis of cis-dichloro- and cis-chloroaquobis(propylenediamine)-chromium(III) cations" @default.
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- W1975927260 doi "https://doi.org/10.1016/0022-1902(67)80294-x" @default.
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