FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1975930550> ?p ?o ?g. }

• W1975930550 endingPage "11573" @default.
• W1975930550 startingPage "11564" @default.
• W1975930550 abstract "Vanadium environments in Keggin oxopolytungstates were characterized by (51)V solid-state MAS NMR spectroscopy. (C(4)H(9))(4)N(+)-, K(+)-, Cs(+)-, as well as mixed Na(+)/Cs(+)- salts of the mono-, di-, and trivanadium substituted oxotungstates, [VW(11)O(40)](4-), [V(2)W(10)O(40)](5-), and [V(3)W(9)O(40)](6-), have been prepared as microcrystalline and crystalline solids. Solid-state NMR spectra report on the local environment of the vanadium site in these Keggin ions via their anisotropic quadrupolar and chemical-shielding interactions. These (51)V fine structure constants in the solid state are determined by the number of vanadium atoms present in the oxoanion core. Surprisingly, the quadrupolar anisotropy tensors do not depend to any significant extent on the nature of the countercations. On the other hand, the chemical-shielding anisotropy tensors, as well as the isotropic chemical shifts, display large variations as a function of the cationic environment. This information can be used as a probe of the local cationic environment in the vanadium-substituted Keggin solids." @default.
• W1975930550 created "2016-06-24" @default.
• W1975930550 creator A5013225612 @default.
• W1975930550 creator A5013852704 @default.
• W1975930550 creator A5032363202 @default.
• W1975930550 creator A5042213638 @default.
• W1975930550 creator A5048662974 @default.
• W1975930550 creator A5062717638 @default.
• W1975930550 date "2004-08-27" @default.
• W1975930550 modified "2023-09-27" @default.
• W1975930550 title "⁵¹V Magic Angle Spinning NMR Spectroscopy of Keggin Anions [PV<i>_n</i>W_12-<i>_n</i>O₄₀]⁽³⁺^<i>n</i>^)-: Effect of Countercation and Vanadium Substitution on Fine Structure Constants" @default.
• W1975930550 cites W1973251313 @default.
• W1975930550 cites W1973264461 @default.
• W1975930550 cites W1980388632 @default.
• W1975930550 cites W1993483407 @default.
• W1975930550 cites W1993665733 @default.
• W1975930550 cites W1996508912 @default.
• W1975930550 cites W2002437230 @default.
• W1975930550 cites W2003607911 @default.
• W1975930550 cites W2008578315 @default.
• W1975930550 cites W2014984772 @default.
• W1975930550 cites W2033476458 @default.
• W1975930550 cites W2037027420 @default.
• W1975930550 cites W2044221005 @default.
• W1975930550 cites W2050956798 @default.
• W1975930550 cites W2057034425 @default.
• W1975930550 cites W2075944119 @default.
• W1975930550 cites W2078364238 @default.
• W1975930550 cites W2089448494 @default.
• W1975930550 cites W2094602042 @default.
• W1975930550 cites W2145250069 @default.
• W1975930550 cites W2159359535 @default.
• W1975930550 cites W2402743136 @default.
• W1975930550 cites W2950657581 @default.
• W1975930550 cites W2952815462 @default.
• W1975930550 cites W2953130956 @default.
• W1975930550 cites W51089849 @default.
• W1975930550 doi "https://doi.org/10.1021/ja0475499" @default.
• W1975930550 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15366903" @default.
• W1975930550 hasPublicationYear "2004" @default.
• W1975930550 type Work @default.
• W1975930550 sameAs 1975930550 @default.
• W1975930550 citedByCount "58" @default.
• W1975930550 countsByYear W19759305502012 @default.
• W1975930550 countsByYear W19759305502013 @default.
• W1975930550 countsByYear W19759305502014 @default.
• W1975930550 countsByYear W19759305502015 @default.
• W1975930550 countsByYear W19759305502016 @default.
• W1975930550 countsByYear W19759305502017 @default.
• W1975930550 countsByYear W19759305502018 @default.
• W1975930550 countsByYear W19759305502020 @default.
• W1975930550 countsByYear W19759305502021 @default.
• W1975930550 countsByYear W19759305502022 @default.
• W1975930550 countsByYear W19759305502023 @default.
• W1975930550 crossrefType "journal-article" @default.
• W1975930550 hasAuthorship W1975930550A5013225612 @default.
• W1975930550 hasAuthorship W1975930550A5013852704 @default.
• W1975930550 hasAuthorship W1975930550A5032363202 @default.
• W1975930550 hasAuthorship W1975930550A5042213638 @default.
• W1975930550 hasAuthorship W1975930550A5048662974 @default.
• W1975930550 hasAuthorship W1975930550A5062717638 @default.
• W1975930550 hasConcept C111429119 @default.
• W1975930550 hasConcept C113196181 @default.
• W1975930550 hasConcept C121332964 @default.
• W1975930550 hasConcept C1276947 @default.
• W1975930550 hasConcept C145148216 @default.
• W1975930550 hasConcept C147789679 @default.
• W1975930550 hasConcept C153202636 @default.
• W1975930550 hasConcept C161790260 @default.
• W1975930550 hasConcept C178790620 @default.
• W1975930550 hasConcept C179104552 @default.
• W1975930550 hasConcept C183882617 @default.
• W1975930550 hasConcept C185592680 @default.
• W1975930550 hasConcept C201370411 @default.
• W1975930550 hasConcept C2778591166 @default.
• W1975930550 hasConcept C32891209 @default.
• W1975930550 hasConcept C43617362 @default.
• W1975930550 hasConcept C46141821 @default.
• W1975930550 hasConcept C4839761 @default.
• W1975930550 hasConcept C504678139 @default.
• W1975930550 hasConcept C55493867 @default.
• W1975930550 hasConcept C62520636 @default.
• W1975930550 hasConcept C66974803 @default.
• W1975930550 hasConcept C67787023 @default.
• W1975930550 hasConcept C70854507 @default.
• W1975930550 hasConcept C71240020 @default.
• W1975930550 hasConcept C8010536 @default.
• W1975930550 hasConcept C84935128 @default.
• W1975930550 hasConcept C85725439 @default.
• W1975930550 hasConceptScore W1975930550C111429119 @default.
• W1975930550 hasConceptScore W1975930550C113196181 @default.
• W1975930550 hasConceptScore W1975930550C121332964 @default.
• W1975930550 hasConceptScore W1975930550C1276947 @default.
• W1975930550 hasConceptScore W1975930550C145148216 @default.
• W1975930550 hasConceptScore W1975930550C147789679 @default.
• W1975930550 hasConceptScore W1975930550C153202636 @default.
• W1975930550 hasConceptScore W1975930550C161790260 @default.
• W1975930550 hasConceptScore W1975930550C178790620 @default.

• next