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• W1975951968 abstract "The Rh(I)-catalyzed addition of alkenyl and aryl MIDA boronates to N-tert-butanesulfinyl aromatic and aliphatic imines proceeds in good yields (up to 99%) and with very high selectivity (98:2 to >99:1). In comparison to trifluoroborates, higher yields and selectivities are observed for the addition to N-tert-butanesulfinyl aromatic imines. This new method expands upon the versatility of the Rh(I)-catalyzed addition of boron reagents to imines, thereby further enabling the synthesis of chiral α-branched amines." @default.
• W1975951968 created "2016-06-24" @default.
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• W1975951968 date "2010-04-13" @default.
• W1975951968 modified "2023-09-26" @default.
• W1975951968 title "Asymmetric Rh(I)-Catalyzed Addition of MIDA Boronates to <i>N</i>-<i>tert</i>-Butanesulfinyl Aldimines: Development and Comparison to Trifluoroborates" @default.
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• W1975951968 doi "https://doi.org/10.1021/jo100318s" @default.
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