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- W1975956290 abstract "Type 1 Cu(II), in native Vietnamese laccase and type 2 Cu-depleted enzyme, and type 2 Cu(II), in native enzyme both in the absence and presence of fluoride, have been examined by Endor spectroscopy. Endor spectra from type 1 Cu(II) are identical in both the native and the type 2 Cu-depleted derivative, and they are characterized by lines due only to protons. The Endor spectrum of type 2 Cu(II) taken at the low-field g∥ extreme shows just one pair of proton lines. Addition of fluoride excess produces the appearance of two magnetically inequivalent nitrogen atoms. A geometry comprising two nitrogen and two fluoride atoms in the equatorial plane is inferred for type 2 copper (Cu) in the presence of fluoride." @default.
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- W1975956290 date "1989-06-01" @default.
- W1975956290 modified "2023-09-26" @default.
- W1975956290 title "Endor spectra of type 1 and type 2 copper centers in Vietnamese laccase" @default.
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- W1975956290 doi "https://doi.org/10.1016/0162-0134(89)80016-9" @default.
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