FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976003218> ?p ?o ?g. }

• W1976003218 endingPage "6365" @default.
• W1976003218 startingPage "6357" @default.
• W1976003218 abstract "To examine possible models for the g = 2.006 resonance seen when the hydroxylated heme-heme oxygenase complex in the Fe(III) state is treated with CO, the reactivities of CO and reducing agents with (py)(2)Fe(III)(OEPO) and [Fe(III)(OEPO)](2) (OEPO is the trianion of octaethyl-meso-hydroxyporphyrin) have been examined. A pyridine solution of (py)(2)Fe(III)(OEPO) reacts in a matter of minutes with zinc amalgam (or with hydrazine) under an atmosphere of dioxygen-free dinitrogen to produce bright-red (py)(2)Fe(II)(OEPOH).2py.0.33H(2)O, which has been isolated in crystalline form. The (1)H NMR spectrum of (py)(2)Fe(II)(OEPOH) in a pyridine-d(5) solution is indicative of the presence of a diamagnetic compound, and no EPR resonance was observed for this compound. Treatment of a solution of (py)(2)Fe(II)(OEPOH) in pyridine-d(5) with carbon monoxide produces spectral changes after a 30 s exposure that are indicative of the formation of diamagnetic (OC)(py)Fe(II)(OEPOH). Treatment of a green pyridine solution of (py)(2)Fe(III)(OEPO) with carbon monoxide reveals a slow color change to deep red over a 16 h period. Although a resonance at g = 2.006 was observed in the EPR spectrum of the sample during the reaction, the isolated product is EPR silent. The spectroscopic features of the final solution are identical to those of a solution formed by treating (py)(2)Fe(II)(OEPOH) with carbon monoxide. Addition of hydrazine to solutions of (OC)(py)Fe(II)(OEPOH) produces red, diamagnetic (OC)(N(2)H(4))Fe(II)(OEPOH).py in crystalline form. The X-ray crystal structures of (py)(2)Fe(II)(OEPOH).2py.0.33H(2)O and (OC)(N(2)H(4))Fe(II)(OEPOH).py have been determined. Solutions of diamagnetic (OC)(N(2)H(4))Fe(II)(OEPOH).py and (OC)(py)Fe(II)(OEPOH) are extremely air sensitive and are immediately converted in a pyridine solution into paramagnetic (py)(2)Fe(III)(OEPO) in the presence of dioxygen." @default.
• W1976003218 created "2016-06-24" @default.
• W1976003218 creator A5009326683 @default.
• W1976003218 creator A5067879544 @default.
• W1976003218 creator A5068969801 @default.
• W1976003218 date "2004-09-08" @default.
• W1976003218 modified "2023-10-18" @default.
• W1976003218 title "Reactions of <i>meso</i>-Hydroxyhemes with Carbon Monoxide and Reducing Agents in Search of the Elusive Species Responsible for the <i>g</i> = 2.006 Resonance of Carbon Monoxide-Treated Heme Oxygenase. Isolation of Diamagnetic Iron(II) Complexes of Octaethyl-<i>m</i><i>eso</i>-hydroxyporphyrin" @default.
• W1976003218 cites W1973002321 @default.
• W1976003218 cites W1981995715 @default.
• W1976003218 cites W1997819288 @default.
• W1976003218 cites W1997847983 @default.
• W1976003218 cites W1998204951 @default.
• W1976003218 cites W2014602178 @default.
• W1976003218 cites W2030200618 @default.
• W1976003218 cites W2032308327 @default.
• W1976003218 cites W2032613908 @default.
• W1976003218 cites W2033166351 @default.
• W1976003218 cites W2034692427 @default.
• W1976003218 cites W2038092263 @default.
• W1976003218 cites W2050806272 @default.
• W1976003218 cites W2054484829 @default.
• W1976003218 cites W2055317690 @default.
• W1976003218 cites W2063140678 @default.
• W1976003218 cites W2063874047 @default.
• W1976003218 cites W2074794066 @default.
• W1976003218 cites W2081628217 @default.
• W1976003218 cites W2084139543 @default.
• W1976003218 cites W2084834790 @default.
• W1976003218 cites W2088841919 @default.
• W1976003218 cites W2089605901 @default.
• W1976003218 cites W2094122546 @default.
• W1976003218 cites W2095132130 @default.
• W1976003218 cites W2121967553 @default.
• W1976003218 cites W2138647586 @default.
• W1976003218 cites W2322802613 @default.
• W1976003218 cites W2950798160 @default.
• W1976003218 cites W2951380517 @default.
• W1976003218 cites W3005141982 @default.
• W1976003218 doi "https://doi.org/10.1021/ic049581+" @default.
• W1976003218 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15446884" @default.
• W1976003218 hasPublicationYear "2004" @default.
• W1976003218 type Work @default.
• W1976003218 sameAs 1976003218 @default.
• W1976003218 citedByCount "17" @default.
• W1976003218 countsByYear W19760032182012 @default.
• W1976003218 countsByYear W19760032182013 @default.
• W1976003218 countsByYear W19760032182014 @default.
• W1976003218 countsByYear W19760032182015 @default.
• W1976003218 countsByYear W19760032182016 @default.
• W1976003218 countsByYear W19760032182017 @default.
• W1976003218 countsByYear W19760032182021 @default.
• W1976003218 countsByYear W19760032182022 @default.
• W1976003218 countsByYear W19760032182023 @default.
• W1976003218 crossrefType "journal-article" @default.
• W1976003218 hasAuthorship W1976003218A5009326683 @default.
• W1976003218 hasAuthorship W1976003218A5067879544 @default.
• W1976003218 hasAuthorship W1976003218A5068969801 @default.
• W1976003218 hasConcept C109214941 @default.
• W1976003218 hasConcept C121332964 @default.
• W1976003218 hasConcept C139210041 @default.
• W1976003218 hasConcept C155647269 @default.
• W1976003218 hasConcept C161790260 @default.
• W1976003218 hasConcept C178790620 @default.
• W1976003218 hasConcept C179104552 @default.
• W1976003218 hasConcept C185592680 @default.
• W1976003218 hasConcept C186423591 @default.
• W1976003218 hasConcept C187961010 @default.
• W1976003218 hasConcept C2779485729 @default.
• W1976003218 hasConcept C46141821 @default.
• W1976003218 hasConcept C512735826 @default.
• W1976003218 hasConcept C535196362 @default.
• W1976003218 hasConcept C71240020 @default.
• W1976003218 hasConcept C75473681 @default.
• W1976003218 hasConceptScore W1976003218C109214941 @default.
• W1976003218 hasConceptScore W1976003218C121332964 @default.
• W1976003218 hasConceptScore W1976003218C139210041 @default.
• W1976003218 hasConceptScore W1976003218C155647269 @default.
• W1976003218 hasConceptScore W1976003218C161790260 @default.
• W1976003218 hasConceptScore W1976003218C178790620 @default.
• W1976003218 hasConceptScore W1976003218C179104552 @default.
• W1976003218 hasConceptScore W1976003218C185592680 @default.
• W1976003218 hasConceptScore W1976003218C186423591 @default.
• W1976003218 hasConceptScore W1976003218C187961010 @default.
• W1976003218 hasConceptScore W1976003218C2779485729 @default.
• W1976003218 hasConceptScore W1976003218C46141821 @default.
• W1976003218 hasConceptScore W1976003218C512735826 @default.
• W1976003218 hasConceptScore W1976003218C535196362 @default.
• W1976003218 hasConceptScore W1976003218C71240020 @default.
• W1976003218 hasConceptScore W1976003218C75473681 @default.
• W1976003218 hasIssue "20" @default.
• W1976003218 hasLocation W19760032181 @default.
• W1976003218 hasLocation W19760032182 @default.
• W1976003218 hasOpenAccess W1976003218 @default.
• W1976003218 hasPrimaryLocation W19760032181 @default.
• W1976003218 hasRelatedWork W1976003218 @default.
• W1976003218 hasRelatedWork W2018543773 @default.
• W1976003218 hasRelatedWork W2148787175 @default.

• next