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- W1976090403 abstract "Infrared photodissociation spectra of (benzene−water−Ar)+ in the 3 μm region were observed by monitoring benzene+ and (benzene−water)+ fragments. The spectral features showed that the Ar atom locates on the benzene ring, preserving the same structure as that of (benzene−water)+, in which the water moiety is bound to the side of benzene+ by the charge−dipole interaction and C−H···O hydrogen bonds. We evaluated the binding energy of (benzene−water)+ to be D0 = 3290 ± 120 cm-1 by analyzing the appearance energy dependence of the fragments. The binding energy of the cluster cation gave us the adiabatic ionization potential of the neutral (benzene−water) cluster, IP0 = 72160 ± 150 cm-1." @default.
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- W1976090403 date "2004-09-10" @default.
- W1976090403 modified "2023-10-14" @default.
- W1976090403 title "Binding Energy of the Benzene−Water Cluster Cation: An Ar-Mediated IR Photodissociation Study" @default.
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- W1976090403 doi "https://doi.org/10.1021/jp047723f" @default.
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