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• W1976136795 abstract "Raman spectroscopy and multivariate curve resolution (Raman-MCR) are combined to yield a powerful spectroscopic method for identifying solute-induced perturbations of solvent molecules. The principles and applications of the resulting solvation-shell spectroscopy are described and illustrated using both numerical model spectra and experimental Raman spectra, including water in acetone and aqueous OH − , as well as of both neutral and ionic acetic acid solutions. The results illustrate the quantitative capabilities of Raman-MCR as a solvation-shell spectroscopy, including fundamental limitations arising from “intensity” and “rotational” ambiguities." @default.
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• W1976136795 date "2012-03-01" @default.
• W1976136795 modified "2023-10-17" @default.
• W1976136795 title "Application of Raman Multivariate Curve Resolution to Solvation-Shell Spectroscopy" @default.
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• W1976136795 doi "https://doi.org/10.1366/11-06442" @default.
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