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- W1976150110 endingPage "1098" @default.
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- W1976150110 abstract "Tetracycline antibiotics, tetracycline, chlortetracycline, demeclocycline, doxycycline, minocycline, methacycline, oxytetracycline, and anhydrotetracycline, are examined by electrospray ionization in a quadrupole ion trap. Studies were undertaken to evaluate the use of metal complexation as an alternative to conventional proton attachment. A variety of metal cationization processes, including attachment of Na+, Mg2+, Ca2+, Co2+, Ni2+, and Cu2+ were probed. Infrared multiphoton photodissociation and collisionally activated dissociation (CAD) were compared for generation of diagnostic fragmentation patterns of protonated and metal cationized tetracyclines. The photodissociation spectra provide a more informative signature, including more low mass ions that are not observed upon CAD. The metal complexes dissociate by pathways that are similar to those observed for the protonated molecules." @default.
- W1976150110 created "2016-06-24" @default.
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- W1976150110 date "1998-10-01" @default.
- W1976150110 modified "2023-10-02" @default.
- W1976150110 title "Identification of tetracycline antibiotics by electrospray ionization in a quadrupole ion trap" @default.
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- W1976150110 doi "https://doi.org/10.1016/s1044-0305(98)00078-6" @default.
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