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- W1976243220 abstract "The thermolytic molecular precursor method was used to introduce site-isolated Ti(IV) centers onto the surface of a mesoporous SBA15 support. The resulting surface Si-OH/Ti-OH sites of the Ti-SBA15 catalysts were modified with a series of (N,N-dimethylamino)trialkylsilanes, Me(2)N-SiMe(2)(R) (where R = Me, (n)Bu, or (n)Oc). Compared with the unmodified catalysts, the surface-modified catalysts are more active in the oxidation of cyclohexene with H(2)O(2) and exhibit a significantly higher selectivity (up to 58%) for cyclohexene oxide formation (vs allylic oxidation products). In situ Fourier transform infrared (FTIR) and diffuse reflectance UV visible (DRUV-vis) spectroscopies were used to probe this phenomenon, and it was determined that active sites with capped titanol centers, (SiO(surface))(3)Ti(OSiR(3)), likely undergo Ti-OOH formation upon addition of H(2)O(2) in a manner analogous to that for active sites of the type (SiO(surface))(3)TiOH. On the basis of the observation of similar Ti-OOH intermediates for both species, the electron-withdrawing effects on the Ti(IV) active site, resulting from the surface modification, are likely responsible for the observed increase in selectivity." @default.
- W1976243220 created "2016-06-24" @default.
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- W1976243220 date "2005-09-16" @default.
- W1976243220 modified "2023-10-05" @default.
- W1976243220 title "Influence of Surface Modification of Ti−SBA15 Catalysts on the Epoxidation Mechanism for Cyclohexene with Aqueous Hydrogen Peroxide" @default.
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- W1976243220 doi "https://doi.org/10.1021/la051182j" @default.
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