FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976245664> ?p ?o ?g. }

• W1976245664 endingPage "389" @default.
• W1976245664 startingPage "374" @default.
• W1976245664 abstract "An investigation has been performed of the adsorption of Ru3(CO)12, α-H4Ru4(CO)12, and Ru6C(CO)17 on γ-Al2O3 and SiO2, and of the structures formed upon decomposition of the initially supported clusters. The extent of Ru3(CO)12 adsorption on γ-Al2O3 strongly depends on the temperature at which the support had been dehydroxylated. Infrared spectra of alumina-supported Ru3(CO)12 suggest that the cluster is adsorbed as a result of interactions between the carbonyl ligands and hydroxyl groups and Lewis acid sites present on the support surface. Similar interactions are proposed for alumina-supported α-H4Ru4(CO)12 and Ru6C(CO)12. Decomposition of the supported clusters produces three surface structures, independent of the original cluster composition. The first structure is characterized by bands at 2045–2050 and 1965–1970 cm−1 and is represented by [Ru(CO)2X2]n. The second and third structures are characterized by bands at 2130–2140, 2060–2070, and 1990–2000 cm−1 and are represented by [Ru(CO)3X2]nand [Ru(CO)4X2]n, respectively. In each of the structures X represents an oxygen atom of the alumina lattice. The nuclearity of the surface structures, n, cannot be defined from the present studies. Complete decarbonylation of the Ru surface structures induces a stronger Ru-support interaction, which may lead to the entry of Ru ions into the support lattice and the formation of surface aluminates. The aluminates are not stable, however, and the initial three structures can be regained by heating in CO. Upon reduction of the supported clusters in H2 at temperatures above 400 °C, Ru microcrystallites appear to be formed. These particles are not stable and the Ru is redispersed into smaller units if the sample is heated in CO above 200 °C. By contrast with γ-Al2O3, the interactions of Ru2(CO)12 with SiO2 are very weak. As a consequence Ru microcrystallites are formed when the supported cluster is reduced in H2 at temperatures above 400 °C." @default.
• W1976245664 created "2016-06-24" @default.
• W1976245664 creator A5033742976 @default.
• W1976245664 date "1980-10-01" @default.
• W1976245664 modified "2023-10-11" @default.
• W1976245664 title "An infrared study of alumina- and silica-supported ruthenium cluster carbonyls" @default.
• W1976245664 cites W1964751532 @default.
• W1976245664 cites W1967678080 @default.
• W1976245664 cites W1992120349 @default.
• W1976245664 cites W1993692719 @default.
• W1976245664 cites W1997422467 @default.
• W1976245664 cites W2006890405 @default.
• W1976245664 cites W2007069731 @default.
• W1976245664 cites W2018267429 @default.
• W1976245664 cites W2018493179 @default.
• W1976245664 cites W2019216116 @default.
• W1976245664 cites W2019619579 @default.
• W1976245664 cites W2030081576 @default.
• W1976245664 cites W2033622061 @default.
• W1976245664 cites W2035209461 @default.
• W1976245664 cites W2050020220 @default.
• W1976245664 cites W2055159685 @default.
• W1976245664 cites W2058465762 @default.
• W1976245664 cites W2061279168 @default.
• W1976245664 cites W2061806156 @default.
• W1976245664 cites W2076085552 @default.
• W1976245664 cites W2082304877 @default.
• W1976245664 cites W2106896282 @default.
• W1976245664 cites W2107555785 @default.
• W1976245664 cites W2119035328 @default.
• W1976245664 cites W2156666173 @default.
• W1976245664 cites W2350117120 @default.
• W1976245664 cites W2952354437 @default.
• W1976245664 cites W3138975019 @default.
• W1976245664 doi "https://doi.org/10.1016/0021-9517(80)90315-2" @default.
• W1976245664 hasPublicationYear "1980" @default.
• W1976245664 type Work @default.
• W1976245664 sameAs 1976245664 @default.
• W1976245664 citedByCount "138" @default.
• W1976245664 countsByYear W19762456642012 @default.
• W1976245664 countsByYear W19762456642017 @default.
• W1976245664 countsByYear W19762456642018 @default.
• W1976245664 countsByYear W19762456642020 @default.
• W1976245664 countsByYear W19762456642022 @default.
• W1976245664 crossrefType "journal-article" @default.
• W1976245664 hasAuthorship W1976245664A5033742976 @default.
• W1976245664 hasConcept C102931765 @default.
• W1976245664 hasConcept C115624301 @default.
• W1976245664 hasConcept C120665830 @default.
• W1976245664 hasConcept C121332964 @default.
• W1976245664 hasConcept C124681953 @default.
• W1976245664 hasConcept C132190689 @default.
• W1976245664 hasConcept C147789679 @default.
• W1976245664 hasConcept C150394285 @default.
• W1976245664 hasConcept C153642686 @default.
• W1976245664 hasConcept C158355884 @default.
• W1976245664 hasConcept C161790260 @default.
• W1976245664 hasConcept C163638829 @default.
• W1976245664 hasConcept C164866538 @default.
• W1976245664 hasConcept C178790620 @default.
• W1976245664 hasConcept C179104552 @default.
• W1976245664 hasConcept C185592680 @default.
• W1976245664 hasConcept C198819137 @default.
• W1976245664 hasConcept C199360897 @default.
• W1976245664 hasConcept C41008148 @default.
• W1976245664 hasConcept C555196967 @default.
• W1976245664 hasConcept C8010536 @default.
• W1976245664 hasConceptScore W1976245664C102931765 @default.
• W1976245664 hasConceptScore W1976245664C115624301 @default.
• W1976245664 hasConceptScore W1976245664C120665830 @default.
• W1976245664 hasConceptScore W1976245664C121332964 @default.
• W1976245664 hasConceptScore W1976245664C124681953 @default.
• W1976245664 hasConceptScore W1976245664C132190689 @default.
• W1976245664 hasConceptScore W1976245664C147789679 @default.
• W1976245664 hasConceptScore W1976245664C150394285 @default.
• W1976245664 hasConceptScore W1976245664C153642686 @default.
• W1976245664 hasConceptScore W1976245664C158355884 @default.
• W1976245664 hasConceptScore W1976245664C161790260 @default.
• W1976245664 hasConceptScore W1976245664C163638829 @default.
• W1976245664 hasConceptScore W1976245664C164866538 @default.
• W1976245664 hasConceptScore W1976245664C178790620 @default.
• W1976245664 hasConceptScore W1976245664C179104552 @default.
• W1976245664 hasConceptScore W1976245664C185592680 @default.
• W1976245664 hasConceptScore W1976245664C198819137 @default.
• W1976245664 hasConceptScore W1976245664C199360897 @default.
• W1976245664 hasConceptScore W1976245664C41008148 @default.
• W1976245664 hasConceptScore W1976245664C555196967 @default.
• W1976245664 hasConceptScore W1976245664C8010536 @default.
• W1976245664 hasIssue "2" @default.
• W1976245664 hasLocation W19762456641 @default.
• W1976245664 hasOpenAccess W1976245664 @default.
• W1976245664 hasPrimaryLocation W19762456641 @default.
• W1976245664 hasRelatedWork W1984527654 @default.
• W1976245664 hasRelatedWork W2053571467 @default.
• W1976245664 hasRelatedWork W2147655058 @default.
• W1976245664 hasRelatedWork W2321305361 @default.
• W1976245664 hasRelatedWork W2809091766 @default.
• W1976245664 hasRelatedWork W2970132751 @default.

• next