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- W1976258093 abstract "Molecular orbital calculations with aristolochic acid I (AAI) and the model compounds 8-nitro-1-naphthoic acid (1,8NNA) and 3-nitro-2-naphthoic acid (2,3NNA) confirm a similar conformation of the nitro and carboxyl groups in these molecules. The ortho isomer 2,3NNA is not mutagenic in the Salmonella strains TA 100 or TA 1537, but the peri-substituted 1,8NNA shows mutagenic activity similar to AAI in TA 100, although it is only weakly active in TA 1537. We propose a mechanism of activation via a cyclic nitrenium ion with an aristolactam structure which is possible only in peri-substituted nitro carboxylic acids." @default.
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- W1976258093 date "1990-11-01" @default.
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- W1976258093 title "The structural basis for the mutagenicity of aristolochic acid" @default.
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- W1976258093 doi "https://doi.org/10.1016/0304-3835(90)90058-6" @default.
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