FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976268037> ?p ?o ?g. }

• W1976268037 endingPage "107" @default.
• W1976268037 startingPage "91" @default.
• W1976268037 abstract "The addition of small amounts of phosphine combustion products (phosphorus oxides and acids) to water vapor resulted in a large increase in the relaxation rate of OH to equilibrium concentrations following H2O photolysis. The thermochemical properties of 17 simple phosphorus species were assembled and the equilibrium densities of the phosphorus species were calculated under typical test conditions. The thermochemical properties of many of the phosphorus species have not been determined but for the purposes of this analysis they were estimated from the results of ab initio quantum chemical calculations available in the literature. Of the phosphorus species examined, eight were selected for construction of a reaction set. Thirteen species (7 HxOy species and 6 HxOyPz species) were ultimately used to assemble a set of 33 reactions which comprise all of the bimolecular reactions (including recombination reactions) likely to participate in the overall reaction chemistry. Rate constant values were estimated using standard methods for the metathesis reactions and using simplified RRKM calculations to estimate the rates of recombination reactions. The increase in the observed rate of OH recovery was well described by this reaction set at the experimental conditions of 1970 K and 532 Torr. The two reaction mechanisms OH + PH2 → HOPO2, H + HOPO2 → H2O + PO2, andH + PO2 → HOPO, OH + H2 → H2O + H, H + HOPO → H2O + PO2 appear to be the predominant pathways for recombination of H and OH radicals to form H2O and for reestablishment of chemical equilibrium when phosphine combustion products are present in the reaction mixture." @default.
• W1976268037 created "2016-06-24" @default.
• W1976268037 creator A5028129425 @default.
• W1976268037 date "1993-07-01" @default.
• W1976268037 modified "2023-09-23" @default.
• W1976268037 title "The influence of phosphorus oxides and acids on the rate of H + OH recombination☆" @default.
• W1976268037 cites W1983605096 @default.
• W1976268037 cites W1993947121 @default.
• W1976268037 cites W1999211965 @default.
• W1976268037 cites W2007509097 @default.
• W1976268037 cites W2015212138 @default.
• W1976268037 cites W2015223196 @default.
• W1976268037 cites W2019229024 @default.
• W1976268037 cites W2027581497 @default.
• W1976268037 cites W2030415783 @default.
• W1976268037 cites W2054077382 @default.
• W1976268037 cites W2063799712 @default.
• W1976268037 cites W2070396197 @default.
• W1976268037 cites W2082940646 @default.
• W1976268037 cites W2156371286 @default.
• W1976268037 cites W2162347547 @default.
• W1976268037 cites W2341283081 @default.
• W1976268037 cites W2789640663 @default.
• W1976268037 cites W2798856947 @default.
• W1976268037 doi "https://doi.org/10.1016/0010-2180(93)90022-u" @default.
• W1976268037 hasPublicationYear "1993" @default.
• W1976268037 type Work @default.
• W1976268037 sameAs 1976268037 @default.
• W1976268037 citedByCount "83" @default.
• W1976268037 countsByYear W19762680372012 @default.
• W1976268037 countsByYear W19762680372013 @default.
• W1976268037 countsByYear W19762680372014 @default.
• W1976268037 countsByYear W19762680372015 @default.
• W1976268037 countsByYear W19762680372016 @default.
• W1976268037 countsByYear W19762680372017 @default.
• W1976268037 countsByYear W19762680372018 @default.
• W1976268037 countsByYear W19762680372019 @default.
• W1976268037 countsByYear W19762680372020 @default.
• W1976268037 countsByYear W19762680372021 @default.
• W1976268037 countsByYear W19762680372022 @default.
• W1976268037 countsByYear W19762680372023 @default.
• W1976268037 crossrefType "journal-article" @default.
• W1976268037 hasAuthorship W1976268037A5028129425 @default.
• W1976268037 hasConcept C104317684 @default.
• W1976268037 hasConcept C105923489 @default.
• W1976268037 hasConcept C10710636 @default.
• W1976268037 hasConcept C121332964 @default.
• W1976268037 hasConcept C139066938 @default.
• W1976268037 hasConcept C147597530 @default.
• W1976268037 hasConcept C147789679 @default.
• W1976268037 hasConcept C148898269 @default.
• W1976268037 hasConcept C156695909 @default.
• W1976268037 hasConcept C161790260 @default.
• W1976268037 hasConcept C175113610 @default.
• W1976268037 hasConcept C178790620 @default.
• W1976268037 hasConcept C179104552 @default.
• W1976268037 hasConcept C183971685 @default.
• W1976268037 hasConcept C185592680 @default.
• W1976268037 hasConcept C2777716191 @default.
• W1976268037 hasConcept C2781442258 @default.
• W1976268037 hasConcept C32909587 @default.
• W1976268037 hasConcept C510538283 @default.
• W1976268037 hasConcept C55493867 @default.
• W1976268037 hasConcept C62520636 @default.
• W1976268037 hasConcept C73051877 @default.
• W1976268037 hasConcept C75473681 @default.
• W1976268037 hasConcept C93391505 @default.
• W1976268037 hasConceptScore W1976268037C104317684 @default.
• W1976268037 hasConceptScore W1976268037C105923489 @default.
• W1976268037 hasConceptScore W1976268037C10710636 @default.
• W1976268037 hasConceptScore W1976268037C121332964 @default.
• W1976268037 hasConceptScore W1976268037C139066938 @default.
• W1976268037 hasConceptScore W1976268037C147597530 @default.
• W1976268037 hasConceptScore W1976268037C147789679 @default.
• W1976268037 hasConceptScore W1976268037C148898269 @default.
• W1976268037 hasConceptScore W1976268037C156695909 @default.
• W1976268037 hasConceptScore W1976268037C161790260 @default.
• W1976268037 hasConceptScore W1976268037C175113610 @default.
• W1976268037 hasConceptScore W1976268037C178790620 @default.
• W1976268037 hasConceptScore W1976268037C179104552 @default.
• W1976268037 hasConceptScore W1976268037C183971685 @default.
• W1976268037 hasConceptScore W1976268037C185592680 @default.
• W1976268037 hasConceptScore W1976268037C2777716191 @default.
• W1976268037 hasConceptScore W1976268037C2781442258 @default.
• W1976268037 hasConceptScore W1976268037C32909587 @default.
• W1976268037 hasConceptScore W1976268037C510538283 @default.
• W1976268037 hasConceptScore W1976268037C55493867 @default.
• W1976268037 hasConceptScore W1976268037C62520636 @default.
• W1976268037 hasConceptScore W1976268037C73051877 @default.
• W1976268037 hasConceptScore W1976268037C75473681 @default.
• W1976268037 hasConceptScore W1976268037C93391505 @default.
• W1976268037 hasIssue "1-2" @default.
• W1976268037 hasLocation W19762680371 @default.
• W1976268037 hasOpenAccess W1976268037 @default.
• W1976268037 hasPrimaryLocation W19762680371 @default.
• W1976268037 hasRelatedWork W189537100 @default.
• W1976268037 hasRelatedWork W1971370386 @default.
• W1976268037 hasRelatedWork W1972429876 @default.

• next