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• W1976331682 endingPage "1555" @default.
• W1976331682 startingPage "1545" @default.
• W1976331682 abstract "Abstract Thermodynamic measurements and reactivity studies are used in estimating (RhRh), (RhH), (RhC) and (RhO) bond dissociation energies (BDE) in octaethylporphyrin rhodium, [(OEP)Rh], complexes. Temperature dependence of the proton NMR line broadening of [(OEP)Rh]2 is used as a kinetic method for estimating the (RhRh) BDE as 16.5±0.8 kcal mol−1. Thermodynamic cycles are presented that provide values for the (RhH) BDE in (OEP)RhH (62 kcal mol−1) and (RhC) BDE in (OEP)RhCHO (58 kcal mol −1). Transfer of bond energy values from organic compounds to the organic fragments in organometallic species is used as a means of establishing general thermodynamic criteria for addition reactions of metal hydrides and metal—metal bonded complexes, with compounds that contain CO and CC multiple bonds. Approximate bond energy analysis is applied to the (OEP)Rh system in anticipating reactivity, estimating (RhC) and (RhO) bond energies and in recognizing steric effects." @default.
• W1976331682 created "2016-06-24" @default.
• W1976331682 creator A5066494794 @default.
• W1976331682 date "1988-01-01" @default.
• W1976331682 modified "2023-09-25" @default.
• W1976331682 title "RhRh, RhH, RhC and RhO bond energies in (OEP)Rh complexes: Thermodynamic criteria for addition of MH and MM bonds to CO and CC multiple bonds" @default.
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• W1976331682 doi "https://doi.org/10.1016/s0277-5387(00)81781-7" @default.
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