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- W1976333423 abstract "In an effort to determine the effects of N6-methylation of the adenine ring on stacking, the molecular aggregation of 9,9′-(α,ω-alkanediyl)bis[6-(dimethylamino)purine] (1) and of 9,9′-(α,ω-alkanediyl)bis[6-(methylamino)purine] (2) were compared with that of 9,9′-(α,ω-alkanediyl)bis[adenine] (3) by NMR spectroscopy. The obtained concentration effects indicate that N6-methylation resulted in an increase in the population of intermolecular aggregates in the buffer solution at pD 7.0, and had an additive effect on the aggregation. It can be interpreted as a hydrophobic effect of the N6-methyl groups. The aggregation of 1 and 2 depended on the length of the polymethylene chains in a similar manner as that of 3, when the measurements were made on the solution of low concentrations. This suggests that the aggregates of 1, 2, and 3 were similar to each other through stacking between two adenine rings. Furthermore, the chemical shifts of the N6-methyl groups were slightly influenced by the length of the polymethyl..." @default.
- W1976333423 created "2016-06-24" @default.
- W1976333423 creator A5000471025 @default.
- W1976333423 date "2000-07-01" @default.
- W1976333423 modified "2023-10-16" @default.
- W1976333423 title "Effect of the N<sup>6</sup>-Methyl Group of the Adenine Ring on the Stacking Interaction" @default.
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- W1976333423 doi "https://doi.org/10.1246/bcsj.73.1621" @default.
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