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- W1976340287 abstract "Die Titelverbindung entsteht durch Reaktion von Tellurtetrachlorid mit Tris(trimethylsilyl)amin in siedendem Toluol. Blaßgelbe Kristalle der Zusammensetzung [Te11N6Cl26]2 · 9C7H8 entstehen beim Abkühlen gesättigter Lösungen. Die Verbindung wird durch das IR-Spektrum und durch eine Kristallstrukturanalyse charakterisiert. Raumgruppe P1, Z = 1, Strukturlösung mit 5912 beobachteten unabhängigen Reflexen, R = 0,043. Gitterkonstanten bei −50°C: a = 1636,2; b = 1692,7; c = 1704,1 pm; α = 60,57 β = 69,59°; γ = 64,29°. Bestimmendes Strukturmotiv des Nitridchlorids sind planare Te5N3-Einheiten, die zwei miteinander kondensierte Te2N2-Viererringe bilden. Zwei asymmetrische Einheiten [Te11N6Cl26] sind über ein Symmetriezentrum miteiander verknüpft; die eingelagerten Toluomoleküle sind ohne bindende Wechselwirkung. Synthesis and Crystal Structure of the Tellurium Nitride Chloride [Te11N6Cl26] The title compound has been prepared by the reaction of tellurium tetrachloride with tris(trimethylsilyl)amine in boiling toluene. Pale yellow crystals of the composition [Te11N6Cl26]2 · 9C7H8 are obtained by cooling of the saturated solution. The compound was characterized by IR spectroscopy and by a crystal structure determination. Space group P1, Z = 1, structure solution with 5912 observed unique reflections, R = 0.043. Lattice dimensions at −50°C: a = 1636.2, b = 1692.7, c = 1704.1 pm, α = 60.57°, β = 69.59°, γ = 64.29°. The dominating structural element of the nitrchloride are planar Te5N3 units forming two four-member Te2N2 rings which are condensed together. Two asymmetric units [Te11N6Cl26] are linked by a centre of symmetry; the intercalated toluene molecules are without binding interactions." @default.
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- W1976340287 date "1996-04-01" @default.
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- W1976340287 title "Synthese und Kristallstruktur des Tellur-Nitridchlorids [Te11N6Cl26]" @default.
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- W1976340287 doi "https://doi.org/10.1002/zaac.19966220430" @default.
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