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- W1976341913 abstract "The first-order rate constants for aquation of Co(NH3)5(DMF)3+ were determined in aqueous perchlorate media. The rate constants were independent of hydrogen ion concentration and ionic strength, but decreased with increasing perchlorate ion concentration. Proton magnetic resonance studies showed that dimethylformamide was not hydrolyzed to formic acid and dimethylamine in the aquation step. Mass-spectrometer studies showed that cobalt–oxygen bond breaking occurred in 98 percent, or more, of the aquation acts. Enthalpies and entropies of activation were determined. It was concluded that aquation occurred by an Id mechanism." @default.
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- W1976341913 date "1976-05-01" @default.
- W1976341913 modified "2023-09-24" @default.
- W1976341913 title "Aquation of (N, Ndimethylformamide) pentaamminecobalt (III) perchlorate in aqueous perchlorate media" @default.
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- W1976341913 doi "https://doi.org/10.1002/kin.550080306" @default.
- W1976341913 hasPublicationYear "1976" @default.
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