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- W1976362320 abstract "The crystal structures of the two title compounds (I and II, respectively) have been solved from partial three-dimensional data by means of SEARCH, and refined by a full-matrix least-squares programme with anisotropic temperature factors of all but the hydrogen atoms to r = 0.042, 0.031, R = 0.078, 0.075. The bond lengths and angles (e.s.d. 0.01 Å, 0.3°) are consistent internally and between the two molecules, as well as with similar values in related molecules. The molecules are centrosymmetric and have adopted the cisoid conformation of the C=C-C=O group. The benzene rings, and the CC(O)C and CCCC systems are planar, with dihedral angles between these groups of 12.0° (I), 9.7° (II) and 12.6° (I), 4.4° (II). Upon irradiation trans-1,2-dibenzoylethylene undergoes a single-crystal-single-crystal transformation to the cis-isomer." @default.
- W1976362320 created "2016-06-24" @default.
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- W1976362320 date "2010-09-02" @default.
- W1976362320 modified "2023-10-11" @default.
- W1976362320 title "Topochemistry. Part XL. 1The crystal structures of trans-1,2-dibenzoyl- and 1,2-di-p-toluylethylene" @default.
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- W1976362320 doi "https://doi.org/10.1002/recl.19780970904" @default.
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