FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976420592> ?p ?o ?g. }

• W1976420592 endingPage "761" @default.
• W1976420592 startingPage "741" @default.
• W1976420592 abstract "Prior studies have recently demonstrated a positive linear covariance in the Sr and Mg contents of abiotic marine carbonates such that the slope of this relation is dependent upon the Sr/Mg ratio of seawater at the time of precipitation. Samples of ancient abiotic marine calcite cements that have undergone diagenesis through alteration by meteoric waters exhibit similar linear trends that range from primary marine ratios to low values that converge to zero. Thus, Sr/Mg ratios in diagenetic precipitates are potential proxies for the reconstruction of past variations in the elemental chemistry of ancient seawater. To expand upon limited existing Sr/Mg data, late Silurian and middle Triassic abiotic calcite cements were analyzed for stable isotope and minor element compositions. Silurian cements from the Pipe Creek Junior Quarry, Grant County, Indiana, show a linear covariance of Sr and Mg concentrations expressed by the following relationship: Sr/Ca = 0.0306 (±0.0091) Mg/Ca + 2.349 × 10−6 (±5.812 × 10−5). Triassic cements from the Cozzo di Lupo Formation, Sicily, Italy, exhibit a linear covariance given by: Sr/Ca = 0.0103 (±0.0009) Mg/Ca + 3.818 × 10−5 (±2.800 × 10−5). To evaluate the mechanisms by which Sr/Mg ratios are preserved in diagenetic calcite, a progressive rock-water interaction model was employed that traces the simultaneous evolution of δ13C, δ18O, Sr, and Mg contents of both fluid and solid phases. Results from modeling indicate that the Sr/Mg ratio of diagenetic calcite is primarily controlled by the ratio of distribution coefficients for Sr and Mg in calcite. When DSr/DMg is equal to unity, covariance of Sr/Ca and Mg/Ca in diagenetic calcite is linear, with a slope equivalent to the Sr/Mg value of the original dissolved solid phase. When DSr/DMg deviates from unity, the incorporation of Sr/Ca and Mg/Ca in diagenetic precipitates becomes progressively non-linear. A general agreement of theoretical and empirical results for Pliocene abiotic calcite cements of Frank and Lohmann (1996) indicates that model simulations adequately represent natural diagenetic settings. Additionally, at rock-water ratios where δ13C has converged to and δ18O has shifted toward original rock composition, elemental contents, and thus the Sr/Mg ratio, are effectively preserved. Thus, retention of original Sr/Mg chemistries is possible across a broad range of rock-water ratios, even where primary δ18O values have been significantly modified. Given the correlation between theoretical and empirical Sr/Mg results, we suggest that variation in the Sr/Mg composition of abiotic calcite cements reflect fluctuations in the Sr/Mg chemistry of ancient seawater." @default.
• W1976420592 created "2016-06-24" @default.
• W1976420592 creator A5040939030 @default.
• W1976420592 creator A5041447936 @default.
• W1976420592 date "2001-03-01" @default.
• W1976420592 modified "2023-09-27" @default.
• W1976420592 title "Sr/Mg variation during rock-water interaction: implications for secular changes in the elemental chemistry of ancient seawater" @default.
• W1976420592 cites W1514503790 @default.
• W1976420592 cites W1530880138 @default.
• W1976420592 cites W1682777677 @default.
• W1976420592 cites W1685068806 @default.
• W1976420592 cites W188681293 @default.
• W1976420592 cites W1964177191 @default.
• W1976420592 cites W1970285508 @default.
• W1976420592 cites W1973082754 @default.
• W1976420592 cites W1976620802 @default.
• W1976420592 cites W1980113659 @default.
• W1976420592 cites W1981926445 @default.
• W1976420592 cites W1985001241 @default.
• W1976420592 cites W1987036576 @default.
• W1976420592 cites W1988378253 @default.
• W1976420592 cites W1991952401 @default.
• W1976420592 cites W1996167059 @default.
• W1976420592 cites W1997055084 @default.
• W1976420592 cites W1999898881 @default.
• W1976420592 cites W2005550073 @default.
• W1976420592 cites W2012316671 @default.
• W1976420592 cites W2014796857 @default.
• W1976420592 cites W2016015255 @default.
• W1976420592 cites W2016346936 @default.
• W1976420592 cites W2024551378 @default.
• W1976420592 cites W2028504381 @default.
• W1976420592 cites W2030820013 @default.
• W1976420592 cites W2032231421 @default.
• W1976420592 cites W2035519495 @default.
• W1976420592 cites W2037056329 @default.
• W1976420592 cites W2037428114 @default.
• W1976420592 cites W2041040421 @default.
• W1976420592 cites W2044536687 @default.
• W1976420592 cites W2044967324 @default.
• W1976420592 cites W2046088045 @default.
• W1976420592 cites W2049381564 @default.
• W1976420592 cites W2052895954 @default.
• W1976420592 cites W2053408869 @default.
• W1976420592 cites W2054539784 @default.
• W1976420592 cites W2056601768 @default.
• W1976420592 cites W2057378841 @default.
• W1976420592 cites W2062746313 @default.
• W1976420592 cites W2063322620 @default.
• W1976420592 cites W2070022169 @default.
• W1976420592 cites W2071160900 @default.
• W1976420592 cites W2082460606 @default.
• W1976420592 cites W2087390324 @default.
• W1976420592 cites W2109293499 @default.
• W1976420592 cites W2114987349 @default.
• W1976420592 cites W2131379501 @default.
• W1976420592 cites W2147427800 @default.
• W1976420592 cites W2157677644 @default.
• W1976420592 cites W2327637686 @default.
• W1976420592 cites W40925381 @default.
• W1976420592 doi "https://doi.org/10.1016/s0016-7037(00)00594-9" @default.
• W1976420592 hasPublicationYear "2001" @default.
• W1976420592 type Work @default.
• W1976420592 sameAs 1976420592 @default.
• W1976420592 citedByCount "33" @default.
• W1976420592 countsByYear W19764205922012 @default.
• W1976420592 countsByYear W19764205922013 @default.
• W1976420592 countsByYear W19764205922014 @default.
• W1976420592 countsByYear W19764205922015 @default.
• W1976420592 countsByYear W19764205922016 @default.
• W1976420592 countsByYear W19764205922017 @default.
• W1976420592 countsByYear W19764205922018 @default.
• W1976420592 countsByYear W19764205922022 @default.
• W1976420592 crossrefType "journal-article" @default.
• W1976420592 hasAuthorship W1976420592A5040939030 @default.
• W1976420592 hasAuthorship W1976420592A5041447936 @default.
• W1976420592 hasConcept C111368507 @default.
• W1976420592 hasConcept C127313418 @default.
• W1976420592 hasConcept C130452526 @default.
• W1976420592 hasConcept C151730666 @default.
• W1976420592 hasConcept C156622251 @default.
• W1976420592 hasConcept C17409809 @default.
• W1976420592 hasConcept C197248824 @default.
• W1976420592 hasConcept C199289684 @default.
• W1976420592 hasConcept C2780191791 @default.
• W1976420592 hasConcept C92720285 @default.
• W1976420592 hasConceptScore W1976420592C111368507 @default.
• W1976420592 hasConceptScore W1976420592C127313418 @default.
• W1976420592 hasConceptScore W1976420592C130452526 @default.
• W1976420592 hasConceptScore W1976420592C151730666 @default.
• W1976420592 hasConceptScore W1976420592C156622251 @default.
• W1976420592 hasConceptScore W1976420592C17409809 @default.
• W1976420592 hasConceptScore W1976420592C197248824 @default.
• W1976420592 hasConceptScore W1976420592C199289684 @default.
• W1976420592 hasConceptScore W1976420592C2780191791 @default.
• W1976420592 hasConceptScore W1976420592C92720285 @default.
• W1976420592 hasIssue "5" @default.
• W1976420592 hasLocation W19764205921 @default.

• next