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- W1976434265 abstract "Durch nukleophile Fluor-Aryl-Substitution an XeF2 mit monosubstituierten Phenylboranen (XC6H4)3B und Fluorphenylboranen (XC6H4)nBF3−n (n = 1 und 2; X = m-F, p-F, m-CF3 und p-CF3) gelangt man zu [XC6H4Xe]+ Salzen mit Arylfluoroborat-Anionen [(XC6H4)nBF4−n]− (n = 2, 1 und 0). Deren thermisches Verhalten und spektroskopische Eigenschaften werden beschrieben. Erste Untersuchungen zur Reaktivität der elektrophilen Arylxenon-Kationen werden vorgestellt. Cations with Xenon-Carbon Bonds. 4 Salts with Monosubstituted Phenyl Xenon Cation: Preparation, Stability and Reactivity. Nucleophilic fluorine aryl substitution reactions with monosubstituted phenylboranes (XC6H4)3B and fluorophenylboranes (XC6H4)nBF3−n (n = 1 and 2; X = m-F, p-F, m-CF3 and p-CF3) on XeF2 lead to the formation of [XC6H4Xe]+ salts with arylfluoroborate anions [(XC6H4)nBF4−n]− (n = 2, 1 and 0). Their thermal behaviour, their spectroscopic properties and first investigations concerning their reactivity are reported." @default.
- W1976434265 created "2016-06-24" @default.
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- W1976434265 date "1993-10-01" @default.
- W1976434265 modified "2023-09-27" @default.
- W1976434265 title "Kationen mit Xenon?Kohlenstoff-Bindung. 4. Salze mit monosubstituiertem Phenylxenon-Kation: Darstellung, Stabilit�t und Reaktivit�t" @default.
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- W1976434265 doi "https://doi.org/10.1002/zaac.19936191006" @default.
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