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- W1976442260 abstract "Methoxymethylierung von Sulfinat-Anionen erfolgt je nach Reaktionsbedingungen bevorzugt am S oder am O. Im Gegensatz zu den Produkten der S-Alkylierung erweisen sich die Produkte der O-Alkylierung, die α-Sulfinyloxy-äther 4, als instabil. Über den Verlauf des Zerfalls von 4 in saurem, „neutralem”︁ und alkalischem Medium wird berichtet. α-Sulfonyl Ethers, 8. Dependence of the Direction of Decomposition of α-Sulfinyloxy Ethers on the Reaction Conditions Depending on reaction conditions methoxymethylation of sulfinate anions proceeds preferentially at the S or at the O atom. In contrast to the products of S-alkylation the products of O-alkylation, the α-sulfinyloxy ethers 4, are unstable. The direction of the decomposition of 4 in acid, „neutral”︁, and alkaline medium is discussed." @default.
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- W1976442260 date "1974-09-01" @default.
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- W1976442260 title "α-Sulfonyl-äther, 8. Abhängigkeit der Zerfallsrichtung von α-Sulfinyloxy-äthern vom Reaktionsmedium" @default.
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- W1976442260 doi "https://doi.org/10.1002/cber.19741070925" @default.
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