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- W1976457773 abstract "Abstract The hydrogenation of the cinnamate ion in aqueous solution with the Co(CN) 5 H 3− ion as a catalyst has been reinvestigated. The salt medium was NaCl; ionic strength 1.0 M. The reaction was followed by extracting cinnamic acid from acidified samples into diethyl ether. The acid thus extracted was determined by IR measurement of the V cc band intensity. By careful procedure, the oxidation of Co(CN) 3− 5 could be kept at a very low level. This was checked during each kinetic run via IR spectroscopy. The activation energy was determined as E a = 14.5 ± 0.5 kcal mol −1 ." @default.
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- W1976457773 date "1983-04-01" @default.
- W1976457773 modified "2023-10-01" @default.
- W1976457773 title "On the hydrogenation of cinnamate ions catalyzed by Co(CN)5H3− ions" @default.
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- W1976457773 doi "https://doi.org/10.1016/0304-5102(83)80014-5" @default.
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