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- W1976462013 abstract "Magnesium is light, abundant and it can store up to 7.6 wt. % of hydrogen forming MgH 2 and accordingly it is a promising material for hydrogen storage. Processing of Mg-based mixtures by high-energy ball milling (HEBM) can produce materials with high level H-sorption properties. In the present report, we display and compare the effects of different nanocrystalline additives (MgF 2 , Fe, NbH 0,89 , FeF 3 , VF 3 ) on the formation of MgH 2 by reactive milling. The H-desorption behavior of the as-prepared nanocomposites is also evaluated. A combined catalytic effect is observed due to the synergic action of MgF 2 and Fe (or NbH 0,89 ) on the hydrogenation rate during processing. The transition metal fluorides promote as well the MgH 2 synthesis. By using more energy-intensive milling conditions and adequate additives in given proportions (e.g. 5 mol. % FeF 3 ), is shown to be very effective for a full and fast synthesis (4 h) of MgH 2 by reactive milling." @default.
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- W1976462013 date "2012-11-01" @default.
- W1976462013 modified "2023-10-17" @default.
- W1976462013 title "Reactive Milling of Magnesium under Hydrogen Using Transition Metals and their Fluorides as Additives" @default.
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- W1976462013 doi "https://doi.org/10.4028/www.scientific.net/ssp.194.232" @default.
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