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- W1976465505 abstract "Fourier transform infrared spectroscopy was used to characterize the stretching vibrations of the ester carbonyl groups and the amide I vibration of the amide group of N-acylphosphatidylethanolamine (N-acylPE) bilayers. To obtain quantitative information about changes in hydration, band profiles were simulated with Gaussian-Lorentzian functions. The results are particularly significant since they probably reflect different changes in the hydrogen-bonding interactions in the polar/apolar interfacial region at the gel-liquid-crystalline phase transition of the N-acylPE bilayers related to the N-acyl chain length. In the same way, the carbonyl ester interfacial region of N-acylPEs is spectroscopically similar to those of phosphatidylethanolamine bilayers, in which two populations of hydrogenbonded ester carbonyl groups were observed. Moreover, our study provides additional data pertinent to the physical basis of the thermotropic phase behaviour of aqueous dispersions of N-acylPEs and the basis of the differences between these bilayers and the more intensively studied phosphatidylcholine and phosphatidylethanolamine bilayers." @default.
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- W1976465505 date "1996-12-01" @default.
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- W1976465505 title "Fourier transform infrared spectroscopic analysis of the ester and amide bands of the hydrated dispersions of N-acylethanolamine phospholipids" @default.
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- W1976465505 doi "https://doi.org/10.1016/s0009-3084(96)02632-1" @default.
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