Matches in SemOpenAlex for { <https://semopenalex.org/work/W1976513099> ?p ?o ?g. }
Showing items 1 to 97 of
97
with 100 items per page.
- W1976513099 endingPage "54" @default.
- W1976513099 startingPage "47" @default.
- W1976513099 abstract "The susceptibility of 2-hydroxyglycal esters i.e., 2,3,4,6-tetra-O-acetyl-1,5-anhydro-d-arabino-hex-1-enitol and its d-lyxo analog towards dimerization to 2,3-unsaturated α,α-trehaloses is described, smoothly occurring in moist dichloromethane or acetone solution in the presence of iodine or boron trifluoride. The reaction involves Ferrier ionization and addition of water at C-1 of the delocalized glycosyl oxocarbenium ion, followed by addition of the hex-2-enopyranose thus formed, with its 1-OH, onto the educt still present. Hydrogenation of the dimers thus formed, i.e., 2,4,6-tri-O-acetyl-3-deoxy-α-d-erythro-hex-2-enopyranosyl 2,4,6-tri-O-acetyl-3-deoxy-α-d-erythro-hex-2-enopyranoside and its d-threo/d-threo analog proceeds with high stereoselectivity to give the peracetylated 3,3′-dideoxy-α,α-trehaloses with d-ribo/d-ribo and d-lyxo/d-lyxo configuration." @default.
- W1976513099 created "2016-06-24" @default.
- W1976513099 creator A5000488234 @default.
- W1976513099 creator A5009681772 @default.
- W1976513099 date "1999-06-01" @default.
- W1976513099 modified "2023-10-09" @default.
- W1976513099 title "3,3′-Dideoxytrehaloses via dimerisation of 2-hydroxyglycal esters" @default.
- W1976513099 cites W1766786055 @default.
- W1976513099 cites W1939816201 @default.
- W1976513099 cites W1966310904 @default.
- W1976513099 cites W1980397054 @default.
- W1976513099 cites W1982414593 @default.
- W1976513099 cites W1985363924 @default.
- W1976513099 cites W1992567311 @default.
- W1976513099 cites W1998940001 @default.
- W1976513099 cites W2000102892 @default.
- W1976513099 cites W2006534539 @default.
- W1976513099 cites W2014765252 @default.
- W1976513099 cites W2017307725 @default.
- W1976513099 cites W2022959849 @default.
- W1976513099 cites W2027875573 @default.
- W1976513099 cites W2028169707 @default.
- W1976513099 cites W2041541662 @default.
- W1976513099 cites W2042760452 @default.
- W1976513099 cites W2048396164 @default.
- W1976513099 cites W2048579489 @default.
- W1976513099 cites W2060202384 @default.
- W1976513099 cites W2061185424 @default.
- W1976513099 cites W2069573785 @default.
- W1976513099 cites W2086047329 @default.
- W1976513099 cites W2090013104 @default.
- W1976513099 cites W2108832942 @default.
- W1976513099 cites W2120644407 @default.
- W1976513099 cites W2125179453 @default.
- W1976513099 cites W2161591232 @default.
- W1976513099 cites W2168474959 @default.
- W1976513099 cites W2172087043 @default.
- W1976513099 cites W2460465637 @default.
- W1976513099 cites W2553731662 @default.
- W1976513099 cites W277046890 @default.
- W1976513099 cites W2952294323 @default.
- W1976513099 cites W2952798332 @default.
- W1976513099 doi "https://doi.org/10.1016/s0008-6215(99)00109-3" @default.
- W1976513099 hasPublicationYear "1999" @default.
- W1976513099 type Work @default.
- W1976513099 sameAs 1976513099 @default.
- W1976513099 citedByCount "10" @default.
- W1976513099 crossrefType "journal-article" @default.
- W1976513099 hasAuthorship W1976513099A5000488234 @default.
- W1976513099 hasAuthorship W1976513099A5009681772 @default.
- W1976513099 hasConcept C138716334 @default.
- W1976513099 hasConcept C155647269 @default.
- W1976513099 hasConcept C161790260 @default.
- W1976513099 hasConcept C178790620 @default.
- W1976513099 hasConcept C178907741 @default.
- W1976513099 hasConcept C181647583 @default.
- W1976513099 hasConcept C185592680 @default.
- W1976513099 hasConcept C196647687 @default.
- W1976513099 hasConcept C2776468994 @default.
- W1976513099 hasConcept C2780400988 @default.
- W1976513099 hasConcept C2780471494 @default.
- W1976513099 hasConcept C2780906977 @default.
- W1976513099 hasConcept C71240020 @default.
- W1976513099 hasConceptScore W1976513099C138716334 @default.
- W1976513099 hasConceptScore W1976513099C155647269 @default.
- W1976513099 hasConceptScore W1976513099C161790260 @default.
- W1976513099 hasConceptScore W1976513099C178790620 @default.
- W1976513099 hasConceptScore W1976513099C178907741 @default.
- W1976513099 hasConceptScore W1976513099C181647583 @default.
- W1976513099 hasConceptScore W1976513099C185592680 @default.
- W1976513099 hasConceptScore W1976513099C196647687 @default.
- W1976513099 hasConceptScore W1976513099C2776468994 @default.
- W1976513099 hasConceptScore W1976513099C2780400988 @default.
- W1976513099 hasConceptScore W1976513099C2780471494 @default.
- W1976513099 hasConceptScore W1976513099C2780906977 @default.
- W1976513099 hasConceptScore W1976513099C71240020 @default.
- W1976513099 hasIssue "1-4" @default.
- W1976513099 hasLocation W19765130991 @default.
- W1976513099 hasOpenAccess W1976513099 @default.
- W1976513099 hasPrimaryLocation W19765130991 @default.
- W1976513099 hasRelatedWork W1963483779 @default.
- W1976513099 hasRelatedWork W1977822664 @default.
- W1976513099 hasRelatedWork W2014923099 @default.
- W1976513099 hasRelatedWork W2033362968 @default.
- W1976513099 hasRelatedWork W2147251683 @default.
- W1976513099 hasRelatedWork W2227584064 @default.
- W1976513099 hasRelatedWork W2952764783 @default.
- W1976513099 hasRelatedWork W4238532182 @default.
- W1976513099 hasRelatedWork W4319655719 @default.
- W1976513099 hasRelatedWork W52093646 @default.
- W1976513099 hasVolume "319" @default.
- W1976513099 isParatext "false" @default.
- W1976513099 isRetracted "false" @default.
- W1976513099 magId "1976513099" @default.
- W1976513099 workType "article" @default.