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- W1976540319 abstract "Correction factors are derived for flow in a thin rectangular channel to account for viscous drag at the edges, an effect not considered in infinite parallel plate models. By a proper choice of coordinates, a universal correction term is shown to be applicable to flow in essentially all practical field-flow fractionation (FFF) channels, which are characterized by a large aspect ratio. Also, by virtue of the diffusion and transit time conditions existing in most FFF channels, the universal correction concept can be extended both to void peaks and retained peaks. In this light, the nature of peak migration is discussed. The analysis leads to a more exact relationship between the retention ratio and measured retention volumes, which paves the way toward improved particle characterization by field-flow fractionation." @default.
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- W1976540319 date "1987-01-01" @default.
- W1976540319 modified "2023-10-16" @default.
- W1976540319 title "Theoretical analysis of edge effects in field-flow fractionation" @default.
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- W1976540319 doi "https://doi.org/10.1016/0009-2509(87)85019-4" @default.
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