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• W1976551617 endingPage "630" @default.
• W1976551617 startingPage "623" @default.
• W1976551617 abstract "Intrinsic bond dissociation energies (BDEs) of selected fluorinated polymers are critically evaluated. Two distinctive approaches were followed. In the first one, according to Wu and Rodgers [E.-C. Wu, A.S. Rodgers, J. Am. Chem. Soc. 98 (1976) 6112–6115], starting from the gas-phase enthalpy of polymerization we obtained the polymer backbone BDE through appropriate thermodynamic cycles. Revised experimental results indicate that the CC BDEs of all the polymers taken into account fall within a limited energy interval, comparable to the average experimental uncertainty. Central to the second methodology adopted, is a model compound approach. Thanks to the large number of reliable thermodynamic data available in the scientific literature and to simple end-capping rules, C2 molecules were chosen as suitable models for infinite linear polymers and alternating copolymers between ethylene and fluorinated olefins. For partially fluorinated polymers, like polyvinylidene fluoride (PVDF), alternating ethylene–tertrafluoroethylene (ETFE) and alternating ethylene–chlorotrifluoroethylene (ECTFE), the weight loss due to HF and HCl evolution during heating experiments was successfully related to the threshold energy Eo(HX) for 1,2-elimination from chemically activated hydrofluoro and hydrofluorochlorocarbons according to the modified Rice–Rampsberger–Kassel (RRKM) unimolecular theory." @default.
• W1976551617 created "2016-06-24" @default.
• W1976551617 creator A5031257322 @default.
• W1976551617 date "2005-04-01" @default.
• W1976551617 modified "2023-09-27" @default.
• W1976551617 title "Thermal stability and bond dissociation energy of fluorinated polymers: A critical evaluation" @default.
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• W1976551617 doi "https://doi.org/10.1016/j.jfluchem.2005.01.008" @default.
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