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• W1976572055 abstract "Since the discovery of anticancer activity and subsequent clinical success of cisplatin (cis-[PtCl2(NH3)2]), platinum-based compounds have since been widely synthesized and studied as potential chemotherapeutic agents. In this sense, three novel nuclease active Pt(II) complexes with general formula; [Pt(NH3)Cl(L)] (1), [Pt(L)2] (2), and K[PtCl2(L)] (3) in which L is 1-H-pyrrole-2-carbaldehyde oxime were synthesized. Characterization of complexes was performed by elemental analysis, FT-IR, 1H NMR and mass spectroscopy measurements. Interaction of complexes (1–3) with calf thymus deoxyribonucleic acid (ct-DNA) was investigated by using electrochemical, spectroelectrochemical methods and cleavage studies. The hyperchromic change in the electronic absorption spectrum of the Pt(II) complexes indicates an electrostatic interaction between the complexes and ct-DNA. Binding constant values between 4.42 × 103 and 5.09 × 103 M−1 and binding side size values between 2 and 3 base pairs were determined from cyclic voltammetry (CV) and differential pulse voltammetry (DPV) studies." @default.
• W1976572055 created "2016-06-24" @default.
• W1976572055 creator A5021824095 @default.
• W1976572055 creator A5032250641 @default.
• W1976572055 date "2014-05-01" @default.
• W1976572055 modified "2023-09-24" @default.
• W1976572055 title "Novel Pt(II) complexes containing pyrrole oxime; synthesis, characterization and DNA binding studies" @default.
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• W1976572055 doi "https://doi.org/10.1016/j.molstruc.2014.02.005" @default.
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