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• W1976598810 abstract "Abstract Oxidative addition reactions of {SeC 4 H(4,6-R) 2 N 2 } 2 with [M(PPh 3 ) 4 ] (M = Pt or Pd) in benzene afforded complexes of composition, [Pt{SeC 4 H(4,6-R) 2 N 2 } 2 (PPh 3 ) 2 ] ( 1 ) and [Pd{η 2 -SeC 4 H(4,6-R) 2 N 2 }{SeC 4 H(4,6-R) 2 N 2 }(PPh 3 )] ( 3 ) (R = H or Me). The former when left in solution dissociated to [Pt{η 2 -SeC 4 H(4,6-R) 2 N 2 }{SeC 4 H(4,6-R) 2 N 2 }(PPh 3 )] ( 2 ) and PPh 3 . Treatment of [PtCl 2 (P ∩ P)] (P ∩ P = dppe or dppp) and NaEC 4 H(4,6-R) 2 N 2 (for E/R = Se/H/Me or Te/Me) gave mononuclear complexes [Pt{EC 4 H(4,6-R) 2 N 2 } 2 (P ∩ P)] ( 4 and 6 ) (R = H or Me, P ∩ P = dppe or dppp) which on leaving for recrystallization in dichloromethane/CDCl 3 solution resulted in trinuclear chalcogenido-bridged complexes [Pt 3 (μ-E) 2 (P ∩ P) 3 ]·2Cl (E = Se or Te) ( 6 ). The latter were also formed when [PtCl 2 (P ∩ P)] (P ∩ P = dppe or dppp) was treated with sodium 2-pyrimidyltellurolate. The substitution reactions between [PdCl 2 (P ∩ P)] (P ∩ P = dppe or dppp) and NaEC 4 H(4,6-R) 2 N 2 (E = Se or Te; R = H or Me) afforded chalcogenido-bridged trinuclear complexes, [Pd 3 (μ-E) 2 (P ∩ P) 3 ]2Cl ( 7 ) (P ∩ P = dppe or dppp). These complexes were characterized by elemental analyses and NMR ( 1 H, 31 P, 77 Se, 125 Te, 195 Pt) spectroscopy. The molecular structures of [Pt(SeC 4 H 3 N 2 ) 2 (PPh 3 ) 2 ] ( 1a ) and [Pd{η 2 -SeC 4 H 3 N 2 }{SeC 4 H 3 N 2 }(PPh 3 )] ( 3a ) were established by single crystal X-ray diffraction analyses. Metal atom in these complexes acquires a distorted squareplanar configuration." @default.
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• W1976598810 date "2012-10-01" @default.
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• W1976598810 title "Reactivity of dipyrimidyldiselenides with [M(PPh3)4] and 2-pyrimidylchalcogenolates with [MCl2(diphosphine)] (M = Pd or Pt)" @default.
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• W1976598810 doi "https://doi.org/10.1016/j.jorganchem.2012.06.036" @default.
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