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- W1976635279 abstract "An electrostatic theory of the effect of the medium on the energy differences between rotational isomers, previously given only for very simple molecules, is generalised to apply to any solute molecule. The theory is applied to 1,1,2-trichloroethane and shown to give good agreement with the experimental values of the energy difference between the rotational isomers in the liquid and vapour states. The proton coupling constants of the rotational isomers can be obtained by use of the theory from the solvent-dependence of the observed coupling constant and are 2·2 and 6·38 c./sec., respectively, for the gauche and trans isomers. Certain exceptional solvents are considered as either preferentially associating with one isomer or preferentially solvating the solute with polar groups in the solvent." @default.
- W1976635279 created "2016-06-24" @default.
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- W1976635279 date "1967-01-01" @default.
- W1976635279 modified "2023-10-06" @default.
- W1976635279 title "Medium effects on rotational equilibria. Part III. The theory for any number of dipoles and its application to 1,1,2-trichloroethane" @default.
- W1976635279 doi "https://doi.org/10.1039/j29670000202" @default.
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