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• W1976647532 abstract "Five versatile non-chelating heterocyclic ligands, benzimidazo[1,2-b]benzo[e]-1-thia-3-azacyclicheptane (bbch), 1,2-bis[(4-pyridinyl)-sulfanylmethyl]benzene (psb), 2,3-bis[(4-pyridinyl)-sulfanylmethyl]quinoxaline (psmq), 2-[(p-pyridinyl)-sulfanylmethyl]-pyrimidine (ppsp), and 2-[(m-pyridinyl)-sulfanylmethyl]pyrimidine (mpsp) were designed and prepared. Self-assembly between silver nitrate and bbch resulted in a coordination polymer [Ag2(bbch)2(NO3)2]n (1) with a double silver atom chain, while treatment of silver perchlorate and bbch under the same conditions generated a discrete mononuclear complex [Ag(bbch)2](ClO4) (2). A 30-membered macrocyclic complex [Ag2(psb)2](ClO4)2 (3) was obtained by the stoichiometric reaction of silver perchlorate and psb. A coordination polymer [Ag(psmq)ClO4]n (4) with a zigzag chain was obtained by the reaction of silver perchlorate and psmq. Reaction of silver nitrate with ppsp and mpsp gave rise to polymers [Ag2(ppsp)2(NO3)2]n (5) and [Ag2(mpsp)2(NO3)2]n (6) with single stranded helical chain structures." @default.
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• W1976647532 date "2001-09-01" @default.
• W1976647532 modified "2023-10-16" @default.
• W1976647532 title "Syntheses and structural characterization of silver(I) complexes with versatile heterocyclic sulfur and nitrogen donor ligands" @default.
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• W1976647532 doi "https://doi.org/10.1016/s0277-5387(01)00879-8" @default.
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